Synergistic effect between UV light and PANI/Co3O4 content on TiO2 composite nanoparticles for room-temperature acetone sensing

被引:21
作者
Lee, Jae-Hyoung [1 ]
Kim, Jin-Young [1 ]
Nam, Myung-Sung [1 ]
Mirzaei, Ali [2 ]
Kim, Hyoun Woo [3 ,4 ]
Kim, Sang Sub [1 ]
机构
[1] Inha Univ, Dept Mat Sci & Engn, Incheon 22212, South Korea
[2] Shiraz Univ Technol, Dept Mat Sci & Engn, Shiraz, Iran
[3] Hanyang Univ, Res Inst Ind Sci, Seoul 04763, South Korea
[4] Hanyang Univ, Div Mat Sci & Engn, Seoul 04763, South Korea
基金
新加坡国家研究基金会;
关键词
Acetone gas sensor; TiO2; Polyaniline; UV illumination; NO2 GAS SENSOR; THIN-FILM; ANATASE TIO2; CO; SENSITIVITY; IRRADIATION; SELECTIVITY; SURFACE; PANI; PERFORMANCE;
D O I
10.1016/j.snb.2022.132868
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Ternary hybrid composites are less explored for gas sensing purposes due to their complexity of structures. However, their complexity brings about a greater potential for resistance changes. In this study, we have syn-thesized a new ternary hybrid composite composed of polyaniline (PANI)-loaded Co3O4-TiO2 composite nano -particles (NPs) for acetone sensing at 25 degrees C. For this purpose, PANI and Co3O4 were added into TiO2 NPs using sol-gel method. The gas sensing characteristics of PANI-TiO2, Co3O4-TiO2 composite NPs and PANI-loaded Co3O4-TiO2 composite NPs sensors were systematically investigated with and without UV illumination (at 25 degrees C). Based on the sensing results, the ternary 0.01 wt% PANI-loaded 0.85TiO2 -0.15 Co3O4 composite NPs revealed the highest response to acetone under UV illumination at 25 degrees C. The enhanced performance of opti-mized gas sensor was due to formation of p-n heterojunctions, promising effects of PANI, and UV light effect. The results obtained herein, highlighted the possibility of making a highly reliable acetone sensor working at 25 degrees C using this compounds or related compounds.
引用
收藏
页数:11
相关论文
共 87 条
[1]   N-doped TiO2 anatase nanoparticles as a highly sensitive gas sensor for NO2 detection: insights from DFT computations [J].
Abbasi, Amirali ;
Sardroodi, Jaber Jahanbin .
ENVIRONMENTAL SCIENCE-NANO, 2016, 3 (05) :1153-1164
[2]   The effect of crystalline phase (anatase, brookite and rutile) and size on the photocatalytic activity of calcined polymorphic titanium dioxide (TiO2) [J].
Allen, Norman S. ;
Mahdjoub, Noredine ;
Vishnyakov, Vladimir ;
Kelly, Peter J. ;
Kriek, Roelof J. .
POLYMER DEGRADATION AND STABILITY, 2018, 150 :31-36
[3]   Nanostructured Metal Oxide-Based Acetone Gas Sensors: A Review [J].
Amiri, Vahid ;
Roshan, Hossein ;
Mirzaei, Ali ;
Neri, Giovanni ;
Ayesh, Ahmad I. .
SENSORS, 2020, 20 (11)
[4]   Synthesis of Co3O4/TiO2 composite by pyrolyzing ZIF-67 for detection of xylene [J].
Bai, Shouli ;
Tian, Ke ;
Tian, Ye ;
Guo, Jun ;
Feng, Yongjun ;
Luo, Ruixian ;
Li, Dianqing ;
Chen, Aifan ;
Liu, Chung Chiun .
APPLIED SURFACE SCIENCE, 2018, 435 :384-392
[5]   The time-dependent process of oxidation of the surface of Bi2Te3 studied by x-ray photoelectron spectroscopy [J].
Bando, H ;
Koizumi, K ;
Oikawa, Y ;
Daikohara, K ;
Kulbachinskii, VA ;
Ozaki, H .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2000, 12 (26) :5607-5616
[6]   Porous Si/SnO2 nanowires heterostructures for H2S gas sensing [J].
Bang, Jae Hoon ;
Choi, Myung Sik ;
Mirzaei, Ali ;
Oum, Wansik ;
Han, Seungmin ;
Kim, Sang Sub ;
Kim, Hyoun Woo .
CERAMICS INTERNATIONAL, 2020, 46 (01) :604-611
[7]   Flexible diode of polyaniline/ITO heterojunction on PET substrate [J].
Bera, A. ;
Deb, K. ;
Kathirvel, V. ;
Bera, T. ;
Thapa, R. ;
Saha, B. .
APPLIED SURFACE SCIENCE, 2017, 418 :264-269
[8]   Investigation of Structural, Optical and Electrical Properties of Co3O4 Nanoparticles [J].
Bhargava, Richa ;
Khan, Shakeel ;
Ahmad, Naseem ;
Ansari, Mohd Mohsin Nizam .
2ND INTERNATIONAL CONFERENCE ON CONDENSED MATTER AND APPLIED PHYSICS (ICC-2017), 2018, 1953
[9]   Understanding the sensing mechanism of polyaniline resistive sensors. Effect of humidity on sensing of organic volatiles [J].
Cavallo, Pablo ;
Acevedo, Diego F. ;
Cecilia Fuertes, M. ;
Soler-Illia, Galo J. A. A. ;
Barbero, Cesar A. .
SENSORS AND ACTUATORS B-CHEMICAL, 2015, 210 :574-580
[10]   A DFT study of the acid-base properties of anatase TiO2 and tetragonal ZrO2 by adsorption of CO and CO2 probe molecules [J].
Chen, Hsin-Yi Tiffany ;
Tosoni, Sergio ;
Pacchioni, Gianfranco .
SURFACE SCIENCE, 2016, 652 :163-171