Synthesis, crystal structure and Hirshfeld surface analysis of naphthalene-2,3-diyl bis(3-benzyloxy)-benzoate

被引：0

作者：

Kumar, H. Anil ^{[1
]}

Selvanandan, S. ^{[2
]}

Srinivasa, H. T. ^{[3
]}

Venkateshappa, G. ^{[4
]}

Palakshamurthy, B. S. ^{[5
]}

机构：

[1] Govt First Grade Coll, Dept Phys, Magadi 562120, Karnataka, India

[2] ACS Coll Engn, Dept Phys, Bangalore 560074, Karnataka, India

[3] Raman Res Inst, C V Raman Ave, Bangalore, Karnataka, India

[4] Tumkur Univ, Dept Chem, UCS, BH Rd, Tumkur 572103, Karnataka, India

[5] Tumkur Univ, Dept PG Studies & Res Phys, UCS, Albert Einstein Block, Tumkur 572103, Karnataka, India

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷

关键词：

crystal structure; naphthalene; Hirshfeld surface; benzoate; INTERMOLECULAR INTERACTIONS;

D O I：

10.1107/S2056989023005571

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C38H28O6, the dihedral angles between the naphthalene ring system and its pendant benzyloxy rings A and B are 88.05 (7) and 80.84 (7)degrees, respectively. The dihedral angles between the A and B rings and their attached phenyl rings are 49.15 (8) and 80.78 (8)degrees, respectively. In the extended structure, the molecules are linked by weak C-H center dot center dot center dot O and C-H center dot center dot center dot pi hydrogen bonds, and pi-pi stacking interactions, which variously generate C(11) chains and R-2(2) (12) loops as part of a three-dimensional network. The Hirshfeld surface [fingerprint contributions = H center dot center dot center dot H (42.3%), C center dot center dot center dot H/H center dot center dot center dot C (40.3%) and O center dot center dot center dot H/H center dot center dot center dot O (15.7%)] and intermolecular interaction energies are reported, with dispersion (E-dis = -428.6 kJ mol(-1)) being the major contributor.

引用

页码：686 / +

页数：12

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