Synthesis of Fused Lactones through Transition-Metal-Catalyzed peri C-H Functionalization

被引：2

作者：

Nishida, Ayako ^{[1
]}

Inai, Yasuhito ^{[1
]}

Usuki, Yoshinosuke ^{[1
]}

Satoh, Tetsuya ^{[1
]}

机构：

[1] Osaka Metropolitan Univ, Grad Sch Sci, Dept Chem, 3-3-138 Sugimoto,Sumiyoshi Ku, Osaka 5588585, Japan

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 12卷 / 05期

关键词：

C-H activation; C-O coupling; Cyclization; Lactone; Palladium; Rhodium; BENZOIC-ACIDS; ACTIVATION; CONSTRUCTION;

D O I：

10.1002/ajoc.202300136

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rhodium(III)-catalyzed dehydrogenative cyclization of 9-anthracenecarboxylic acids and 2-substituted 1-naphthoic acids proceeds through peri C-H bond cleavages to produce fused lactones. These aromatic carboxylic acids also undergo dehydrogenative coupling with styrenes and successive Wacker-type cyclization under palladium catalysis to construct 3-benzylidenebenzo[de]isochromen-1-one frameworks.

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页数：5

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