Sintered Polycrystalline BiVO4 Pellet for Stable X-Ray Detector with Low Detection Limit

被引:41
作者
Jia, Shanshan [1 ]
Xiao, Yingrui [1 ]
Bu, Nuo [1 ]
Li, Nan [1 ]
Li, Deng [1 ]
Yang, Zhou [1 ]
Liu, Shengzhong [1 ,2 ]
机构
[1] Shaanxi Normal Univ, Inst Adv Energy Mat, Sch Mat Sci & Engn,Shaanxi Engn Lab Adv Energy Tec, Key Lab Appl Surface & Colloid Chem,Minist Educ,Sh, Xian 710119, Peoples R China
[2] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
基金
中国国家自然科学基金;
关键词
dark current drift; low detection limits; stability; X-ray detectors; PEROVSKITE SINGLE-CRYSTALS; METAL HALIDE PEROVSKITES;
D O I
10.1002/adfm.202213563
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Semiconductors based on Bi element show large attenuation coefficients to X-ray photons and have been recognized as candidates for X-ray detectors. However, the application of stable Bi-based oxide materials to X-ray detectors has been rarely investigated. In this research, the X-ray response of a BiVO4 pellet has been studied. It has been found that the BiVO4 pellet has a large resistivity of 1.3 x 10(12) omega cm, negligible current drift of 6.18 x 10(-8) nA cm(-1) s(-1) V-1 under electrical bias and mobility lifetime product, mu tau, of 1.75 x 10(-4) cm(2) V-1, which renders the pellet with an X-ray sensitivity of 241.3 mu C Gy(air)(-1) cm(-2) and a detection limit of 62 nGy(air) s(-1) under 40 KVp X-ray illumination and 40 V bias voltage. The BiVO4 pellet also shows operational stability under steady X-ray illumination with total dose of 2.01 Gy(air), equal to the dose of 20 000 medical chest X-ray inspections. This research reveals the potential application of BiVO4 in X-ray detection devices and inspires further research in this area.
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页数:7
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