A Study on the Characteristics of a Pt/TiO2 Catalyst Prepared by Liquid-Phase Ruduction for Formaldehyde Oxidation at Room Temperature

被引:0
作者
Kim, Jae Heon [1 ]
Jang, Younghee [1 ]
Kim, Geo Jong [2 ]
Kim, Sung Chul [3 ]
Kim, Sung Su [3 ,4 ]
机构
[1] Grad Sch Kyonggi Univ, Dept Environm Energy Engn, Suwon 16227, South Korea
[2] Korea Res Inst Chem Technol, Daejeon Si 34114, South Korea
[3] Kyonggi Univ, Dept Environm Energy Engn, Suwon 16227, South Korea
[4] Kyonggi Univ, Dept Environm Energy Engn, Suwon 16227, South Korea
来源
APPLIED CHEMISTRY FOR ENGINEERING | 2023年 / 34卷 / 06期
关键词
Liquid-phase reduction; Formaldehyde; Pt/TiO2; Catalyst; Oxidation state; HCHO; GAS; CO;
D O I
10.14478/ace.2023.1096
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Modern society spends more than 80% of its daily life indoors, emphasizing the need for attention to indoor air pollution due to the improvement in living standards. In this study, the performance and reaction characteristics of the Pt/TiO2 catalysts prepared by liquid-phase reduction for the removal of formaldehyde (HCHO), one of the indoor air pollutants, at room temperature without the need for additional light or heat were investigated. As a result, it showed that catalysts prepared by the same method showed approximately 40-80% various activities depending on the type of TiO2. XRD, BET, and XPS analyses were performed to investigate the particle size, crystal structure, specific surface area, and O/Ti molar ratio of the support material, and it revealed that the correlation between the properties and performance was insignificant. To explore the oxidation reaction pathway of formaldehyde (HCHO), in situ DRIFT analysis using carbon monoxide and H-2-TPR was perfomed. The results revealed that the performance was demonstrated by the oxidation state of the active metal and the adsorption -de-sorption characteristics of the adsorbate species.
引用
收藏
页码:612 / 618
页数:6
相关论文
共 50 条
[21]   Mild Preoxidation Treatment of Pt/TiO2 Catalyst and Its Enhanced Low Temperature Formaldehyde Decomposition [J].
Shi, Kangzhong ;
Wang, Lei ;
Li, Long ;
Zhao, Xuejuan ;
Chen, Yuanyuan ;
Hua, Zelin ;
Li, Xiaobao ;
Gu, Xiaoli ;
Li, Licheng .
CATALYSTS, 2019, 9 (08)
[22]   Oxidation of gaseous formaldehyde with ozone over MnOx/TiO2 catalysts at room temperature (25 °C) [J].
Kim, Minsu ;
Park, Eunseuk ;
Jurng, Jongsoo .
POWDER TECHNOLOGY, 2018, 325 :368-372
[23]   Low-Temperature Total Oxidation of Toluene over Assembled Pt/TiO2 Catalyst [J].
Ao Ping ;
Xu Xiang-Sheng ;
Xu Xiao-Xiao ;
Li Jia-Heng ;
Yan Xin-Huan .
ACTA PHYSICO-CHIMICA SINICA, 2014, 30 (05) :950-956
[24]   Characteristics of the HCHO oxidation reaction over Pt/TiO2 catalysts at room temperature: The effect of relative humidity on catalytic activity [J].
Kwon, Dong Wook ;
Seo, Phil Won ;
Kim, Geo Jong ;
Hong, Sung Chang .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 163 :436-443
[25]   Deactivation and regeneration of Pt/TiO2 nanosheet-type catalysts with exposed (001) facets for room temperature oxidation of formaldehyde [J].
Nie, Longhui ;
Zhou, Peng ;
Yu, Jiaguo ;
Jaroniec, Mietek .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2014, 390 :7-13
[26]   One-Step Hydrothermal/Solvothermal Preparation of Pt/TiO2: An Efficient Catalyst for Biobutanol Oxidation at Room Temperature [J].
Lei, Lijun ;
Cao, Qianyue ;
Ma, Jiachen ;
Hou, Fengxiao .
MOLECULES, 2024, 29 (07)
[27]   Sodium-Promoted Pd/TiO2 for Catalytic Oxidation of Formaldehyde at Ambient Temperature [J].
Zhang, Changbin ;
Li, Yaobin ;
Wang, Yafei ;
He, Hong .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2014, 48 (10) :5816-5822
[28]   Formaldehyde Oxidation on Pd/TiO2 Catalysts at Room Temperature: The Effects of Surface Oxygen Vacancies [J].
Yaobin Li ;
Chunying Wang ;
Changbin Zhang ;
Hong He .
Topics in Catalysis, 2020, 63 :810-816
[29]   Enhanced formaldehyde oxidation on CeO2/AlOOH-supported Pt catalyst at room temperature [J].
Yan, Zhaoxiong ;
Xu, Zhihua ;
Yu, Jiaguo ;
Jaroniec, Mietek .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2016, 199 :458-465
[30]   A TiO2/C catalyst having biomimetic channels and extremely low Pt loading for formaldehyde oxidation [J].
Liu, Wei ;
Gong, Yutao ;
Li, Xueping ;
Luo, Cai-wu ;
Liu, Congmin ;
Chao, Zi-sheng .
RSC ADVANCES, 2019, 9 (07) :3965-3971