Visible-Light-Induced Difunctionalization of the C-C Bond of Alkylidenecyclopropanes with Acyl Chlorides

被引：1

作者：

Ding, Chuan ^{[1
]}

Huang, Peng-Fei ^{[1
]}

Xiong, Biquan ^{[1
]}

Tang, Ke-Wen ^{[1
]}

Liu, Yu ^{[1
]}

机构：

[1] Hunan Inst Sci & Technol, Dept Chem & Chem Engn, Yueyang 414006, Peoples R China

来源：

CATALYSTS | 2023年 / 13卷 / 06期

基金：

中国国家自然科学基金;

关键词：

difunctionalization; photocatalysis; ring opening; acyl chlorides; MEDIATED CYCLOADDITION; ACID-CHLORIDES; LEWIS; METHYLENECYCLOPROPANES; CYCLIZATION; TRANSFORMATIONS; REARRANGEMENT; GENERATION; IMINES;

D O I：

10.3390/catal13060919

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new and powerful visible-light-induced difunctionalization of the C-C & sigma;-bond of alkylidenecyclopropanes via a ring-opening process was developed. Importantly, acyl chlorides are used as both acyl and Cl sources. This strategy provides an effective route for the difunctionalization of the C-C bond with an acyl radical and Cl- to construct a new C-C bond and a C-Cl bond in one pot. In addition, it has a wide range of substrates and can tolerate various functional groups.

引用

页数：15

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