Customized dielectric-magnetic balance enhanced electromagnetic wave absorption performance in CuxS/CoFe2O4 composites

被引:58
|
作者
Zheng, Tingting [1 ,2 ]
Zhang, Yan [2 ]
Jia, Zirui [3 ]
Zhu, Jiahui [2 ]
Wu, Guanglei [2 ]
Yin, Pengfei [1 ]
机构
[1] Sichuan Agr Univ, Coll Sci, Yaan 625014, Peoples R China
[2] Qingdao Univ, Inst Mat Energy & Environm, Coll Mat Sci & Engn, State Key Lab Biofibers & Eco Text, Qingdao 266071, Peoples R China
[3] Qingdao Univ, Coll Chem & Chem Engn, Qingdao 266071, Shandong, Peoples R China
关键词
CuxS; The synergistic effect; Snowflake-shaped; Electromagnetic wave absorption; MICROWAVE; NANOSHEETS; NANOPARTICLES;
D O I
10.1016/j.cej.2022.140876
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
2D transition metal sulfide compounds (CuxS) have gained much interest in electromagnetic wave absorption. However, the high conductivity of CuxS results in inferior absorption performance. To solve this problem, magnetic component (CoFe2O4) is compounded with CuxS to build the novel electromagnetic wave absorber with extraordinary structures. CoFe2O4 not only contributes to adjusting the electromagnetic parameters, but also enhances the electromagnetic wave attenuation ability and regulates the absorption band. In this work, snowflake-shaped and nanoflower-shaped CuxS/CoFe2O4 composites were successfully fabricated by regulating different metal salts and solvents. Reasonable collocation of dielectric and magnetic components avoids the impedance mismatch, enhancing conduction loss, polarization loss, magnetic loss. The results show that nanoflower-shaped CuS/CoFe2O4 exhibits electromagnetic wave (EMW) absorption performance with the min-imum reflection loss (RLmin) of-57.60 dB and the maxima effective absorption band (EABmax) of 4.0 GHz. Further, as the morphology changes to snowflake, the RLmin of Cu2S/CoFe2O4 increases to -66.58 dB, whose EABmax is 6.64 GHz at 2.1 mm, and the main absorption peaks shift to X-band. This work provides a versatile strategy for copper base sulfide on excellent and tunable EMW absorption performance.
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页数:10
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