Fluorescent probes based on cellulose for sensitive detection of Fe3+and its applications

被引:6
作者
Zeng, Heyang [1 ]
Yang, Xinjie [1 ]
Yang, Yaohong [1 ]
Liu, Li [1 ]
Guo, Haiyang [2 ]
Xie, Linkun [1 ]
Chai, Xijuan [1 ]
Xu, Kaimeng [1 ]
Du, Guanben [1 ]
Zhang, Lianpeng [1 ]
机构
[1] Southwest Forestry Univ, Yunnan Prov Key Lab Wood Adhes & Glued Prod, Kunming 650224, Yunnan, Peoples R China
[2] Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing Key Lab Mol Recognit & Sensing, Jiaxing 314001, Peoples R China
基金
中国国家自然科学基金;
关键词
Cellulose; Fluorescent probe; Cellulose fluorescent films; WATER; REMOVAL;
D O I
10.1016/j.indcrop.2024.118178
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Iron is closely related to human life and is widely used in industrial production. It is also the highest essential trace element in the human body. A high concentration of Fe3+ is a common water pollutant that can enter the human body through the water cycle and food chain. In this paper, a novel fluorescent probe AC-NA-OH with sensitive response to Fe3+ was designed and synthesized by modifying microcrystalline cellulose (MCC). Probe AC-NA-OH can quickly and sensitively identify Fe3+ (LOD = 0.11 mu M). The reaction mechanism of AC-NA-OH was verified through X-ray photoelectron spectroscopy and density functional theory (DFT) calculations. There was a good linear relationship between the fluorescence intensity of AC-NA-OH and the concentration of Fe3+, while the fluorescence changes from yellow to colorless. In addition, the probe AC-NA-OH has been successfully applied to the detection of Fe3+ in actual water samples, and the cellulose fluorescent films loaded with probe AC-NA-OH can serve as a convenient tool for detecting Fe3+.
引用
收藏
页数:8
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