Robust Ruthenium Phosphide Catalyst for Hydrogenation of Sulfur-Containing Nitroarenes

被引：27
|
作者：
Ishikawa, Hiroya [1 ]
Nakatani, Naoki [2 ]
Yamaguchi, Sho [1 ,2 ]
Mizugaki, Tomoo [1 ,3 ]
Mitsudome, Takato [1 ,4 ]
机构：
[1] Osaka Univ, Grad Sch Engn Sci, Dept Mat Engn Sci, Toyonaka, Osaka 5608531, Japan
[2] Tokyo Metropolitan Univ, Fac & Grad Sch Sci, Dept Chem, Hachioji, Tokyo 1920397, Japan
[3] Osaka Univ, Inst Open & Transdisciplinary Res Initiat OTRI, Innovat Catalysis Sci Div, Suita, Osaka 5650871, Japan
[4] Japan Sci & Technol Agcy JST, PRESTO, Kawaguchi, Saitama 3330012, Japan
来源：
ACS CATALYSIS | 2023年 / 13卷 / 08期
关键词：
hydrogenation; heterogeneous catalyst; phosphide; ruthenium; nitroarene; organosulfur compound; SELECTIVE HYDROGENATION; CHEMOSELECTIVE HYDROGENATION; FUNCTIONALIZED NITROARENES; NITRO-COMPOUNDS; REDUCTION; NITROBENZENE; ADSORPTION; SURFACES; DESIGN;
D O I：
10.1021/acscatal.3c00128
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Development of robust metal catalysts for the hydrogenation of sulfur-containing nitroarenes is challenging because the sulfur atom strongly poisons the active metal sites of the catalyst. We herein report that ruthenium phosphide nanoparticles (Ru2P/SiO2) act as a highly active and robust catalyst for the hydrogenation of sulfur-containing nitroarenes, with 34 times higher activity than that obtained with Ru nanoparticles. Various sulfurcontaining nitroarenes were hydrogenated under 1 bar of H2 and the corresponding anilines, including some important pharmaceutical intermediates, were obtained in high yields. The study results revealed that the electronic and geometrical effects of P surrounding Ru species in Ru2P/SiO2 are crucial to boost the activity and durability against sulfur poisoning.
引用
收藏
页码：5744 / 5751
页数：8
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