Robust Ruthenium Phosphide Catalyst for Hydrogenation of Sulfur-Containing Nitroarenes

被引：33

作者：

Ishikawa, Hiroya ^{[1
]}

Nakatani, Naoki ^{[2
]}

Yamaguchi, Sho ^{[1
,2
]}

Mizugaki, Tomoo ^{[1
,3
]}

Mitsudome, Takato ^{[1
,4
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Mat Engn Sci, Toyonaka, Osaka 5608531, Japan

[2] Tokyo Metropolitan Univ, Fac & Grad Sch Sci, Dept Chem, Hachioji, Tokyo 1920397, Japan

[3] Osaka Univ, Inst Open & Transdisciplinary Res Initiat OTRI, Innovat Catalysis Sci Div, Suita, Osaka 5650871, Japan

[4] Japan Sci & Technol Agcy JST, PRESTO, Kawaguchi, Saitama 3330012, Japan

来源：

ACS CATALYSIS | 2023年 / 13卷 / 08期

关键词：

hydrogenation; heterogeneous catalyst; phosphide; ruthenium; nitroarene; organosulfur compound; SELECTIVE HYDROGENATION; CHEMOSELECTIVE HYDROGENATION; FUNCTIONALIZED NITROARENES; NITRO-COMPOUNDS; REDUCTION; NITROBENZENE; ADSORPTION; SURFACES; DESIGN;

D O I：

10.1021/acscatal.3c00128

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Development of robust metal catalysts for the hydrogenation of sulfur-containing nitroarenes is challenging because the sulfur atom strongly poisons the active metal sites of the catalyst. We herein report that ruthenium phosphide nanoparticles (Ru2P/SiO2) act as a highly active and robust catalyst for the hydrogenation of sulfur-containing nitroarenes, with 34 times higher activity than that obtained with Ru nanoparticles. Various sulfurcontaining nitroarenes were hydrogenated under 1 bar of H2 and the corresponding anilines, including some important pharmaceutical intermediates, were obtained in high yields. The study results revealed that the electronic and geometrical effects of P surrounding Ru species in Ru2P/SiO2 are crucial to boost the activity and durability against sulfur poisoning.

引用

页码：5744 / 5751

页数：8

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