Advances in MOFs and their derivatives for non-noble metal electrocatalysts in water splitting

被引:62
作者
Gao, Guoliang [1 ]
Chen, Xueli [1 ]
Han, Lu [1 ]
Zhu, Guang [1 ]
Jia, Jin [1 ]
Cabot, Andreu [2 ,3 ]
Sun, Zixu [4 ]
机构
[1] Suzhou Univ, Key Lab Spin Electron & Nanomat Anhui Higher Educ, Suzhou 234000, Peoples R China
[2] Catalonia Inst Energy Res IRECSant Adria de Besos, Barcelona 08930, Spain
[3] Catalan Inst Res & Adv Studies ICREA, Pg Lluis Companys 23, Barcelona 08010, Spain
[4] Henan Univ, Sch Mat Sci & Engn, Key Lab Special Funct Mat, Minist Educ, Kaifeng 475004, Peoples R China
基金
中国国家自然科学基金;
关键词
Water splitting; Electrocatalysis; Metal-organic framework; MOF-derivative; Hydrogen evolution reaction; Oxygen evolution reaction; ELECTROCHEMICAL HYDROGEN EVOLUTION; DOPED POROUS CARBON; ORGANIC-FRAMEWORK; OXYGEN EVOLUTION; BIFUNCTIONAL ELECTROCATALYST; HIGH-PERFORMANCE; HIGHLY EFFICIENT; ALKALINE-MEDIUM; ACTIVE-SITES; IN-SITU;
D O I
10.1016/j.ccr.2023.215639
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Green hydrogen is generated by water electrolysis using renewable energy sources. For green hydrogen to become cost-effective in front of hydrogen production from fossil fuels, highly active, efficient, and durable electrocatalysts based on abundant and low-cost elements need to be developed. Great efforts have been invested in designing and engineering water-splitting electrocatalysts with optimized compositions and architecture. In this last direction, metal-organic framework (MOF) compounds have received particular attention on account of their high specific surface area (SSA) and excellent chemical stability. This work affords an overview of the latest progress in the design, engineering, and application of MOFs and their derivatives as electrocatalysts in water splitting. It further discusses the challenges encountered and the new research directions and application prospects. First, the characteristics and advantages of MOF electrocatalysts and the main mechanism of water electrolysis are introduced. Next, the research progress on the application of MOFs and their derivatives in water electrolysis is reviewed, with special emphasis on the preparation, modification, and catalytic activity of the catalysts. Finally, the present challenges and future development prospects of MOFs as water-splitting electrocatalysts are discussed. Overall, this review aims to provide new insights into the design and synthesis principles of MOF materials, promoting their practical application in water splitting, and further broadening their future uses.
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页数:28
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