Structure-induced luminescence and bioactivities of Zinc(II) complexes with 2-(2,4-dichlorophenoxy)-N?-[pyridin-2-ylmethylene]acetohydrazide

被引：5

作者：

Gusev, Alexey ^{[1
]}

Braga, Elena ^{[1
]}

Karmazina, Alexandra ^{[1
]}

Karmazin, Andrey ^{[1
]}

Konnik, Oleg ^{[1
]}

Kiskin, Mikhail ^{[2
]}

Baryshnikov, Glib ^{[3
]}

Linert, Wolfgang ^{[4
]}

机构：

[1] VI Vernadsky Crimean Fed Univ, Simferopol 295007, Crimea, Russia

[2] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

[3] Linkoping Univ, Dept Sci & Technol, Lab Organ Elect, SE-60174 Norrkoping, Sweden

[4] Vienna Univ Technol, Inst Appl Phys, Wiedner Hauptstr 8-10, A-1040 Vienna, Austria

来源：

INORGANICA CHIMICA ACTA | 2023年 / 551卷

关键词：

Zn complex; Hydrazone; 4-D; Crystal structure; Luminescence; Bioactivities; EXCITATION-DEPENDENT EMISSION; SCHIFF-BASE; ZN(II) COMPLEXES; PHOTOLUMINESCENCE; CRYSTAL; LIGANDS;

D O I：

10.1016/j.ica.2023.121481

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure and photophysical properties of the series of Zn(II) complex with the hydrazone ligand, 2-(2,4dichlorophenoxy)-N '-[1-pyridin-2-ylmethylene]acetohydrazide, and different counter anions have been synthesized and characterized by single crystal X-ray diffraction, FT-IR, elemental analyses and ESI-MS. X-ray crystallography has proved the neutral or monoanionic form of ligand upon coordination. All complexes are mononuclear with the tetra/penta/hexacoordinated zinc atoms. The diverse supramolecular architectures of the complexes show that counter-anions have significant impacts on the structures. Furthermore DFT, luminescence properties, antibacterial and herbicide activities of the complexes have been investigated were carried out as well.

引用

页数：10

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