A novel epoxy coating with nanocatalytic anticorrosion performance achieved by single-atom Fe-N-C catalyst

In view of the critical importance of oxygen to corrosion evolution, to starve corrosion via depleting oxy-gen in coatings is a promising strategy. In this work, a novel nanocatalytic anticorrosion concept is pro-posed to design new coating with outstanding corrosion resistance. Different from the passive barrier of traditional coatings and self-repair after corrosion of current stimuli-feedback coatings, such coating could spontaneously eliminate internal diffused oxygen and greatly suppress the corrosion process. As a proof of concept, single-atom Fe-N-C electrocatalyst with isolated FeN4 active sites is synthesized by a simple confined carbonization method, exhibiting excellent oxygen reduction performance (E1/2 = 0.902 V). In composite coating, the evenly dispersed Fe-N-C compensates for the coating defects and serves as oxygen scavengers, which could actively adsorb and consume ambient oxygen, thereby pre-venting oxygen penetration to the metal substrate surface, eliminating the oxygen contribution to corro-sion and significantly boosting the anticorrosion performance of epoxy coating. This in-situ mediation for oxygen in coating prevents metal substrate from receiving new supply of oxygen, while imparting active anticorrosion property to the coating.(c) 2022 Elsevier Inc. All rights reserved.