Naphthalenediimide-based nanoarchitectonics for a fluorescent chemosensor with highly selective and sensitive detection of cyanide ions

被引：6

作者：

Gawade, Vilas K. ^{[1
]}

Jadhav, Ratan W. ^{[2
]}

Chari, Vishnu R. ^{[2
]}

Hangarge, Rahul V. ^{[3
]}

Bhosale, Sheshanath V. ^{[1
]}

机构：

[1] Cent Univ Karanataka, Sch Chem Sci, Dept Chem, Kalaburagi 585367, Karanataka, India

[2] Goa Univ, Sch Chem Sci, Taleigao Plateau 403206, Goa, India

[3] Tai Gowalkar Mahavidyalaya, Dept Chem, Nagpur 441106, India

来源：

ANALYTICAL METHODS | 2023年 / 15卷 / 30期

关键词：

PROBE; CHEMODOSIMETER; RECOGNITION; ANIONS;

D O I：

10.1039/d3ay00615h

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A naphthalenediimide (NDI)-based highly potential chemosensor for the detection of cyanide has been synthesized successfully in several steps. The NDI-based probe displayed high selectivity and sensitivity towards cyanide ions in fluorescence 'turn-off' mode over other ions used in this study. The naked-eye, UV-vis absorbance and fluorescence methods are employed to investigate the sensing performance of probe 1 toward CN- ion detection. The limit of detection for CN- ions was calculated to be 4.11 x 10(-7) M. Moreover, the Stern-Volmer quenching constant and fluorescence quenching efficiency of CN- ions were estimated to be 1.1 x 10(5) M and 88.81%, respectively. Job's plot showed a 1 : 1 stoichiometric complexation reaction between probe 1 and CN- ions. For practical applications, probe 1 was efficiently applied for the detection of CN- ions using a paper strip method.

引用

页码：3727 / 3734

页数：8

共 28 条

[1] Naphthalene diimides: perspectives and promise [J].

Bhosale, Sheshanath, V ;

Al Kobaisi, Mohammad ;

Jadhav, Ratan W. ;

Morajkar, Pranay P. ;

Jones, Lathe A. ;

George, Subi .

CHEMICAL SOCIETY REVIEWS, 2021, 50 (17) :9845-9998

[2] Applications of Supramolecular Anion Recognition [J].

Busschaert, Nathalie ;

Caltagirone, Claudia ;

Van Rossom, Wim ;

Gale, Philip A. .

CHEMICAL REVIEWS, 2015, 115 (15) :8038-8155

[3] A Selective, Colorimetric, and Fluorescent Chemodosimeter for Relay Recognition of Fluoride and Cyanide Anions Based on 1,1′-Binaphthyl Scaffold [J].

Dong, Ming ;

Peng, Yu ;

Dong, Yu-Man ;

Tang, Ning ;

Wang, Ya-Wen .

ORGANIC LETTERS, 2012, 14 (01) :130-133

[4] A fluorescent turn-on probe for cyanide anion detection based on an AIE active cobalt(II) complex [J].

Gabr, Moustafa T. ;

Pigge, F. Christopher .

DALTON TRANSACTIONS, 2018, 47 (06) :2079-2085

[5] Expanded Bodipy Dyes: Anion Sensing Using a Bodipy Analog with an Additional Difluoroboron Bridge [J].

Guliyev, Ruslan ;

Ozturk, Seyma ;

Sahin, Ertan ;

Akkaya, Engin U. .

ORGANIC LETTERS, 2012, 14 (06) :1528-1531

[6] A reversible fluorescent chemosensor for cyanide in 100% aqueous solution [J].

Guo, Yuan-Yuan ;

Tang, Xiao-Liang ;

Hou, Feng-Ping ;

Wu, Jiang ;

Dou, Wei ;

Qin, Wen-Wu ;

Ru, Jia-Xi ;

Zhang, Guo-Lin ;

Liu, Wei-Sheng ;

Yao, Xiao-Jun .

SENSORS AND ACTUATORS B-CHEMICAL, 2013, 181 :202-208

[7] TURN-ON fluorescence detection of cyanide using an ensemble system consisting of a dansyl-based cationic probe and dicyanovinyl derivative [J].

Jeong, Eunhye ;

Yoon, Soyoung ;

Lee, Hyun Sung ;

Kumar, Ashwani ;

Chae, Pil Seok .

DYES AND PIGMENTS, 2019, 162 :348-357

[8] A Diketopyrrolopyrrole-Based Colorimetric and Fluorescent Probe for Cyanide Detection [J].

Jeong, Young-Hwan ;

Lee, Chi-Hwa ;

Jang, Woo-Dong .

CHEMISTRY-AN ASIAN JOURNAL, 2012, 7 (07) :1562-1566

[9] Interdigitated Hydrogen Bonds: Electrophile Activation for Covalent Capture and Fluorescence Turn-On Detection of Cyanide [J].

Jo, Junyong ;

Olasz, Andras ;

Chen, Chun-Hsing ;

Lee, Dongwhan .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (09) :3620-3632

[10] A reaction based colorimetric chemosensor for the detection of cyanide ion in aqueous solution [J].

Kim, Ick Jin ;

Ramalingam, Manivannan ;

Son, Young-A. .

SENSORS AND ACTUATORS B-CHEMICAL, 2017, 246 :319-326

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