Hydrogen production in microwave discharge in water solutions of ethanol at atmospheric pressure

被引：10

作者：

Batukaev, Timur S. ^{[1
]}

Bilera, Igor V. ^{[1
]}

Krashevskaya, Galina V. ^{[1
,2
]}

Lebedev, Yuri A. ^{[1
,3
]}

Epstein, Iren L. ^{[1
]}

机构：

[1] Russian Acad Sci TIPS RAS, AV Topchiev Inst Petrochem Synth, Moscow, Russia

[2] Natl Res Nucl Univ MEPhI, Moscow, Russia

[3] Russian Acad Sci TIPS RAS, AV Topchiev Inst Petrochem Synth, Leninsky Ave 29, Moscow 119991, Russia

来源：

PLASMA PROCESSES AND POLYMERS | 2023年 / 20卷 / 06期

关键词：

ethanol decomposition; hydrogen production; microwave plasma in liquid; PLASMA; GAS; HYDROCARBONS; GENERATION; CONVERSION;

D O I：

10.1002/ppap.202300015

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Gas chromatography, optical emission spectroscope, high speed video camera were used to study the microwave discharge ignited near the end of the microwave antenna in aqueous solution of ethanol at different ethanol content and different incident microwave power. The pressure above the surface of liquid was close to atmospheric pressure. The main gas products were H-2, CO, C2H2, CH4, C2H4. H-2 (approximate to 60 vol%) and CO (approximate to 30 vol%) are predominated. The composition of the reaction products in a microwave discharge is practically independent of incident power and ethanol content in the solution, but the total flow rate of gas products at the system output increases with an increase in the incident power and the ethanol content in solution. Best obtained characteristics of process of hydrogen production were: flow rate of hydrogen was of 3240 mL/min, concentration of hydrogen in gas mixture on the discharge outlet was of 59 vol%, maximum energy efficiency of hydrogen production was of 324 NL/kWh.

引用

页数：10

共 53 条

[1] Hydrogen production by methane decomposition: A review [J].

Abbas, Hazzim F. ;

Daud, W. M. A. Wan .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (03) :1160-1190

[2]

[Anonymous], NIST Chemical Kinetics Database, Standard Reference Database 17, Version 7.0 (Web Version), DOI DOI 10.1107/S0021889809016690.109

[3]

[Anonymous], SOFTW CALC FITT PLAS

[4]

Arutyunov V. S., 2021, COMBUST PLASMA CHEM, V19, P245, DOI [10.18321/cpc462, DOI 10.18321/CPC462]

[5] Production of Hydrogen-Rich Synthesis Gas by Pulsed Atmospheric Plasma Submerged in Mixture of Water with Ethanol [J].

Bardos, L. ;

Barankova, H. ;

Bardos, A. .

PLASMA CHEMISTRY AND PLASMA PROCESSING, 2017, 37 (01) :115-123

[6] EVALUATED KINETIC DATA FOR COMBUSTION MODELING [J].

BAULCH, DL ;

COBOS, CJ ;

COX, RA ;

ESSER, C ;

FRANK, P ;

JUST, T ;

KERR, JA ;

PILLING, MJ ;

TROE, J ;

WALKER, RW ;

WARNATZ, J .

JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1992, 21 (03) :411-734

[7] Steam reforming of ethanol into hydrogen-rich gas using microwave Ar/water "tornado" - Type plasma [J].

Bundaleska, N. ;

Tsyganov, D. ;

Tatarova, E. ;

Dias, F. M. ;

Ferreira, C. M. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (11) :5663-5670

[8] Hydrogen Generation by Pulsed Gliding Arc Discharge Plasma with Sprays of Alcohol Solutions [J].

Burlica, Radu ;

Shih, Kai-Yuan ;

Hnatiuc, Bogdan ;

Locke, Bruce R. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (15) :9466-9470

[9] Hydrogen production by conversion of ethanol using atmospheric pressure microwave plasmas [J].

Czylkowski, D. ;

Hrycak, B. ;

Miotk, R. ;

Jasinski, M. ;

Dors, M. ;

Mizeraczyk, J. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (40) :14039-14044

[10] Review and evaluation of hydrogen production methods for better sustainability [J].

Dincer, Ibrahim ;

Acar, Canan .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (34) :11094-11111

← 1 2 3 4 5 6 →