Advances in CO2 activation by frustrated Lewis pairs: from stoichiometric to catalytic reactions

被引：46
作者：
Khan, Md. Nasim [1 ,2 ]
van Ingen, Yara [1 ]
Boruah, Tribani [1 ]
Mclauchlan, Adam [1 ]
Wirth, Thomas [2 ]
Melen, Rebecca L. [1 ]
机构：
[1] Cardiff Univ, Cardiff Catalysis Inst, Sch Chem, Translat Res Hub, Maindy Rd, Cardiff CF24 4HQ, Wales
[2] Cardiff Univ, Sch Chem, Main Bldg,Pk Pl, Cardiff CF10 3AT, Wales
来源：
CHEMICAL SCIENCE | 2023年 / 14卷 / 47期
关键词：
CARBON-DIOXIDE; HOMOGENEOUS HYDROGENATION; CAPTURE; CONVERSION; CHEMISTRY; PRODUCTS; CHALLENGES; REDUCTION; PERFORMANCE; ABSORPTION;
D O I：
10.1039/d3sc03907b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The rise of CO2 concentrations in the environment due to anthropogenic activities results in global warming and threatens the future of humanity and biodiversity. To address excessive CO2 emissions and its effects on climate change, efforts towards CO2 capture and conversion into value adduct products such as methane, methanol, acetic acid, and carbonates have grown. Frustrated Lewis pairs (FLPs) can activate small molecules, including CO2 and convert it into value added products. This review covers recent progress and mechanistic insights into intra- and inter-molecular FLPs comprised of varying Lewis acids and bases (from groups 13, 14, 15 of the periodic table as well as transition metals) that activate CO2 in stoichiometric and catalytic fashion towards reduced products.
引用
收藏
页码：13661 / 13695
页数：35
相关论文
共 221 条
[51]   Reactions of Boron Amidinates with CO2 and CO and Other Small Molecules [J].
Dureen, Meghan A. ;
Stephan, Douglas W. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (38) :13559-13568
[52]   The Chemistry of a Non-Interacting Vicinal Frustrated Phosphane/Borane Lewis Pair [J].
Elmer, Lisa-Maria ;
Kehr, Gerald ;
Daniliuc, Constantin G. ;
Siedow, Melanie ;
Eckert, Hellmut ;
Tesch, Matthias ;
Studer, Armido ;
Williams, Kamille ;
Warren, Timothy H. ;
Erker, Gerhard .
CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (25) :6056-6068
[53]   Impacts of the Catalyst Structures on CO2 Activation on Catalyst Surfaces [J].
Etim, Ubong J. ;
Zhang, Chenchen ;
Zhong, Ziyi .
NANOMATERIALS, 2021, 11 (12)
[54]   A strained intramolecular P/Al-FLP and its reactivity toward allene [J].
Federmann, Patrick ;
Bosse, Tamino ;
Wolff, Siad ;
Cula, Beatrice ;
Herwig, Christian ;
Limberg, Christian .
CHEMICAL COMMUNICATIONS, 2022, 58 (97) :13451-13454
[55]   Synthesis of Intramolecular P/Al-Based Frustrated Lewis Pairs via Aluminum-Tin-Exchange and their Reactivity toward CO2 [J].
Federmann, Patrick ;
Mueller, Robert ;
Beckmann, Fabian ;
Lau, Caroline ;
Cula, Beatrice ;
Kaupp, Martin ;
Limberg, Christian .
CHEMISTRY-A EUROPEAN JOURNAL, 2022, 28 (25)
[56]   Reactivity of a model of B3P3-doped nanographene with up to three CO2 molecules [J].
Ferrer, Maxime ;
Alkorta, Ibon ;
Elguero, Jose ;
Oliva-Enrich, Josep M. .
SCIENTIFIC REPORTS, 2023, 13 (01)
[57]   Emissions are still rising: ramp up the cuts [J].
Figueres, Christiana ;
Le Quere, Corinne ;
Mahindra, Anand ;
Baete, Oliver ;
Whiteman, Gail ;
Peters, Glen ;
Guan, Dabo .
NATURE, 2018, 564 (7734) :27-30
[58]   On the concept of frustrated Lewis pairs [J].
Fontaine, Frederic-Georges ;
Stephan, Douglas W. .
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2017, 375 (2101)
[59]   Metal-free reduction of CO2 [J].
Fontaine, Frederic-Georges ;
Stephan, Douglas W. .
CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY, 2017, 3 :28-32
[60]   Cooperative Lewis Pairs Based on Late Transition Metals: Activation of Small Molecules by Platinum(0) and B(C6F5)3 [J].
Forrest, Sebastian J. K. ;
Clifton, Jamie ;
Fey, Natalie ;
Pringle, Paul G. ;
Sparkes, Hazel A. ;
Wass, Duncan F. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (07) :2223-2227
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