Advances in CO2 activation by frustrated Lewis pairs: from stoichiometric to catalytic reactions

被引：46
作者：
Khan, Md. Nasim [1 ,2 ]
van Ingen, Yara [1 ]
Boruah, Tribani [1 ]
Mclauchlan, Adam [1 ]
Wirth, Thomas [2 ]
Melen, Rebecca L. [1 ]
机构：
[1] Cardiff Univ, Cardiff Catalysis Inst, Sch Chem, Translat Res Hub, Maindy Rd, Cardiff CF24 4HQ, Wales
[2] Cardiff Univ, Sch Chem, Main Bldg,Pk Pl, Cardiff CF10 3AT, Wales
来源：
CHEMICAL SCIENCE | 2023年 / 14卷 / 47期
关键词：
CARBON-DIOXIDE; HOMOGENEOUS HYDROGENATION; CAPTURE; CONVERSION; CHEMISTRY; PRODUCTS; CHALLENGES; REDUCTION; PERFORMANCE; ABSORPTION;
D O I：
10.1039/d3sc03907b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The rise of CO2 concentrations in the environment due to anthropogenic activities results in global warming and threatens the future of humanity and biodiversity. To address excessive CO2 emissions and its effects on climate change, efforts towards CO2 capture and conversion into value adduct products such as methane, methanol, acetic acid, and carbonates have grown. Frustrated Lewis pairs (FLPs) can activate small molecules, including CO2 and convert it into value added products. This review covers recent progress and mechanistic insights into intra- and inter-molecular FLPs comprised of varying Lewis acids and bases (from groups 13, 14, 15 of the periodic table as well as transition metals) that activate CO2 in stoichiometric and catalytic fashion towards reduced products.
引用
收藏
页码：13661 / 13695
页数：35
相关论文
共 221 条
[1]   A review of the global climate change impacts, adaptation, and sustainable mitigation measures [J].
Abbass, Kashif ;
Qasim, Muhammad Zeeshan ;
Song, Huaming ;
Murshed, Muntasir ;
Mahmood, Haider ;
Younis, Ijaz .
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2022, 29 (28) :42539-42559
[2]   P-H Functionalized Al/P-Based Frustrated Lewis Pairs in Dipolar Activation and Hydrophosphination: Reactions with CO2 and SO2 [J].
Aders, Niklas ;
Keweloh, Lukas ;
Pleschka, Damian ;
Hepp, Alexander ;
Layh, Marcus ;
Rogel, Friedhelm ;
Uhl, Werner .
ORGANOMETALLICS, 2019, 38 (14) :2839-2852
[3]   A review for Metal-Organic Frameworks (MOFs) utilization in capture and conversion of carbon dioxide into valuable products [J].
Al-Rowaili, Fayez Nasir ;
Zahid, Umer ;
Onaizi, Sagheer ;
Khaled, Mazen ;
Jamal, Aqil ;
AL-Mutairi, Eid M. .
JOURNAL OF CO2 UTILIZATION, 2021, 53
[4]  
[Anonymous], 2017, Angew. Chem.
[5]   Metal Triflimidates: Better than Metal Triflates as Catalysts in Organic Synthesis - The Effect of a Highly Delocalized Counteranion [J].
Antoniotti, Sylvain ;
Dalla, Vincent ;
Dunach, Elisabet .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (43) :7860-7888
[6]   Geminal Phosphorus/Aluminum-Based Frustrated Lewis Pairs: C-H versus C≡C Activation and CO2 Fixation [J].
Appelt, Christian ;
Westenberg, Hauke ;
Bertini, Federica ;
Ehlers, Andreas W. ;
Slootweg, J. Chris ;
Lammertsma, Koop ;
Uhl, Werner .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (17) :3925-3928
[7]   Catalysis research of relevance to carbon management: Progress, challenges, and opportunities [J].
Arakawa, H ;
Aresta, M ;
Armor, JN ;
Barteau, MA ;
Beckman, EJ ;
Bell, AT ;
Bercaw, JE ;
Creutz, C ;
Dinjus, E ;
Dixon, DA ;
Domen, K ;
DuBois, DL ;
Eckert, J ;
Fujita, E ;
Gibson, DH ;
Goddard, WA ;
Goodman, DW ;
Keller, J ;
Kubas, GJ ;
Kung, HH ;
Lyons, JE ;
Manzer, LE ;
Marks, TJ ;
Morokuma, K ;
Nicholas, KM ;
Periana, R ;
Que, L ;
Rostrup-Nielson, J ;
Sachtler, WMH ;
Schmidt, LD ;
Sen, A ;
Somorjai, GA ;
Stair, PC ;
Stults, BR ;
Tumas, W .
CHEMICAL REVIEWS, 2001, 101 (04) :953-996
[8]   Catalysis for the Valorization of Exhaust Carbon: from CO2 to Chemicals, Materials, and Fuels. Technological Use of CO2 [J].
Aresta, Michele ;
Dibenedetto, Angela ;
Angelini, Antonella .
CHEMICAL REVIEWS, 2014, 114 (03) :1709-1742
[9]  
Ashley A. E., 2012, FRUSTRATED LEWIS PAI, V334
[10]   Non-Metal-Mediated Homogeneous Hydrogenation of CO2 to CH3OH [J].
Ashley, Andrew E. ;
Thompson, Amber L. ;
O'Hare, Dermot .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (52) :9839-9843
12345678910