Silver-catalyzed Reductive Formylation of Amines with Carbon Dioxide

被引：2

作者：

Uema, Seiya ^{[1
]}

Sekine, Kenshiro ^{[1
]}

Aoshima, Ryotaro ^{[1
]}

Saito, Kodai ^{[1
]}

Yamada, Tohru ^{[1
]}

机构：

[1] Keio Univ, Dept Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan

来源：

CHEMISTRY LETTERS | 2023年 / 52卷 / 07期

基金：

日本学术振兴会;

关键词：

Carbon dioxide; Formylation; Silver catalyst; N-FORMYLATION; MOLECULAR-HYDROGEN; CO2; TRANSFORMATION; FUNCTIONALIZATION; PHENYLSILANE; ACTIVATION; FLUORIDE; SOLVENT;

D O I：

10.1246/cl.230153

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formylation of amines with carbon dioxide was examined in the presence of a catalytic amount of silver (II) picolinate and phenylsilane as a reductant. The reaction proceeded under base-free and mild conditions. The reaction conditions were successfully applied to both primary and secondary amines to afford the corresponding formamide derivatives in high yields. The formylation of amino acids, such as the proline and phenylalanine derivatives, proceeded by the present method to afford the corresponding formylated amine without racemization.

引用

页码：546 / 548

页数：3

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