Asymmetric Catalytic Transformations of Aza-ortho- and Aza-para-Quinone Methides

被引：8

作者：

Zurro, Mercedes ^{[1
]}

Maestro, Aitor ^{[2
,3
]}

机构：

[1] Univ Alcala, IRYCIS, Dept Quim Organ & Quim Inorgan, Alcala De Henares 28805, Madrid, Spain

[2] Univ Basque Country, UPV EHU, Dept Organ Chem 1, Paseo Univ 7, Vitoria 01006, Spain

[3] Karl Franzens Univ Graz, NAWI Graz, Inst Chem, Heinrichstr 28, A-8010 Graz, Austria

来源：

CHEMCATCHEM | 2023年 / 15卷 / 13期

关键词：

asymmetric synthesis; aza-ortho-quinone methides; aza-para-quinone methides; metal catalysis; organocatalysis; 4+2 CYCLOADDITION; ENANTIOSELECTIVE SYNTHESIS; 1,6-CONJUGATE ADDITION; PALLADIUM; CONSTRUCTION; YLIDES;

D O I：

10.1002/cctc.202300500

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalytic methodologies for the derivatization of aza-QM have recently appeared in the literature and involve organocatalytic and organometallic approaches. This review aims at analyzing the diverse catalytic systems involving chiral NHC carbenes, phosphoric acids, phosphoramidites, phosphine and copper and palladium catalysis showing its applicability for the synthesis of a diverse away of N-containing compounds which in many cases have biological activity.

引用

页数：24

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