Aluminum Alloys as Anodes for Aluminum Batteries

被引:4
作者
Bandiera, M. [1 ]
Pavesi, A. [1 ]
Valota, G. [1 ]
Abello, M. A. [1 ]
Trombetta, V. [1 ]
Daga, M. [1 ]
Fiocchi, C. [1 ]
Bonfanti, A. [1 ]
Mancini, A. [1 ]
Bertasi, F. [1 ]
机构
[1] Brembo SpA, GCF Res & Dev, I-24040 Stezzano, Italy
关键词
THIN ELECTROLYTE LAYERS; ATMOSPHERIC CORROSION; METALS; SI;
D O I
10.1149/1945-7111/ad11ac
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The manuscript investigates the synthesis and characterization of Aluminum alloys, comprising Si, Ti and B as alloying elements, as anodes for Al-ion batteries. Deposition/stripping measurements, impedance spectroscopy, metallographic, energy dispersive X-ray spectroscopy (EDXS) and X-ray diffraction (XRD) techniques unveil the complex interplay existing between the microstructures of the alloys and the obtained electrochemical performance. Prototype cycling and post-mortem battery failure analysis are performed as well. It is demonstrated that a remarkable improvement in the: a) oxidation/reduction currents and overvoltages; and b) interfacial stability with the electrolyte; can be obtained, with respect to a conventional Al anode.
引用
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页数:8
相关论文
共 33 条
[1]   Recent Achievements in Experimental and Computational Studies of Positive Electrode Materials for Nonaqueous Ca- and Al-Ion Batteries [J].
Alfaruqi, Muhammad Hilmy ;
Lee, Seunggyeong ;
Kang, Hyokyeong ;
Sambandam, Balaji ;
Mathew, Vinod ;
Hwang, Jang-Yeon ;
Kim, Jaekook .
JOURNAL OF PHYSICAL CHEMISTRY C, 2022, 126 (22) :9209-9227
[2]  
Andreatta F., 2007, European Federation of Corrosion Publications Number 45, Local Probe Techniques for Corrosion Research, pp. 126
[3]  
Bertasi Federico, 2020, SAE International Journal of Advances and Current Practices in Mobility, P966, DOI 10.4271/2020-01-1625
[4]  
Bertasi F., 2022, Italian Patent Application, Patent No. [102022000024522, 10202200002452]
[5]   Toward a Magnesium-Iodine Battery [J].
Bertasi, Federico ;
Sepehr, Fatemeh ;
Pagot, Gioele ;
Paddison, Stephen J. ;
Di Noto, Vito .
ADVANCED FUNCTIONAL MATERIALS, 2016, 26 (27) :4860-4865
[6]   A Key concept in Magnesium Secondary Battery Electrolytes [J].
Bertasi, Federico ;
Hettige, Chaminda ;
Sepehr, Fatemeh ;
Bogle, Xavier ;
Pagot, Gioele ;
Vezzu, Keti ;
Negro, Enrico ;
Paddison, Stephen J. ;
Greenbaum, Steve G. ;
Vittadello, Michele ;
Di Noto, Vito .
CHEMSUSCHEM, 2015, 8 (18) :3069-3076
[7]   Beyond Lithium-Based Batteries [J].
Biemolt, Jasper ;
Jungbacker, Peter ;
van Teijlingen, Tess ;
Yan, Ning ;
Rothenberg, Gadi .
MATERIALS, 2020, 13 (02)
[8]   Reactivity of Succinic Anhydride at Lithium and Graphite Electrodes [J].
Charton, Christopher ;
Santos-Pena, Jesus ;
Biller, Agnes ;
De Vito, Eric ;
Galiano, Herve ;
Le Digabel, Matthieu ;
Lemordant, Daniel .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2017, 164 (07) :A1454-A1463
[9]   Review of current progress in non-aqueous aluminium batteries [J].
Craig, Ben ;
Schoetz, Theresa ;
Cruden, Andrew ;
de Leon, Carlos Ponce .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2020, 133
[10]   An Electrochemical Immunosensor Based on a Self-Assembled Monolayer Modified Electrode for Label-Free Detection of α-Synuclein [J].
Ge, Chuang-Ye ;
Rahman, Md. Mahbubur ;
Zhang, Wei ;
Lopa, Nasrin Siraj ;
Jin, Lei ;
Yoon, Sujin ;
Jang, Hohyoun ;
Xu, Guang-Ri ;
Kim, Whangi .
SENSORS, 2020, 20 (03)