Simultaneously removal of phosphorous and COD for purification of organophosphorus wastewater by catalytic ozonation over CaO

被引：19

作者：

Zhou, Lilong ^{[1
]}

Wang, Shenghao ^{[1
]}

Li, Zhengjie ^{[1
]}

Cao, Xuepu ^{[1
]}

Liu, Runjing ^{[1
]}

Yun, Jimmy ^{[1
,2
]}

机构：

[1] Hebei Univ Sci & Technol, Coll Chem & Pharmaceut Engn, Shijiazhuang 050018, Hebei, Peoples R China

[2] Univ New South Wales, Sch Chem Engn, Sydney, NSW 2052, Australia

来源：

JOURNAL OF WATER PROCESS ENGINEERING | 2023年 / 51卷

基金：

中国国家自然科学基金;

关键词：

Catalytic ozonation; CaO; Organophosphorus; Reactive radicals; COD and total phosphorous removal; PHOSPHATE; MINERALIZATION; MECHANISM; CLAY;

D O I：

10.1016/j.jwpe.2022.103397

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Organic phosphorous wastewater is very hard to be purified which need to remove both COD and phosphorous. The treatment process of organic phosphorous wastewater is commonly complicated. In this work, CaO has been used as the catalyst and precipitant for the treatment of organophosphorus wastewater by catalytic ozonation. Compared with CeO2, MnO2 and MgO, CaO shows excellent catalytic performance for the removal of COD. Additionally, the generated PO33 can be removed by Ca2+. Ca2+ can catalyze the reaction between O-3 and H2O to generate active oxygen species, such as (OH)-O-center dot, -O-center dot(2), O-1(2). Besides, various conditions, namely, amount of catalyst, O-3 flow rate, substrate concentration and pH for the degradation of Tetrakis Hydroxymethyl Phosphonium Sulfate (THPS) wastewater by catalytic ozonation over CaO have been optimized to determine the optimal parameter conditions. Finally, the excess Ca2+ in the solution can be removed by the addition of CO2.

引用

页数：10

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