Carbon Monoxide and Propylene Catalytic Oxidation Activity of Noble Metals (M = Pt, Pd, Ag, and Au) Loaded on the Surface of Ce0.875Zr0.125O2 (110)

被引:1
作者
Zhang, Chenxi [1 ,2 ]
Cao, Xuesong [2 ]
Guo, Lili [1 ]
Fang, Zhihao [1 ]
Feng, Di [1 ]
Sun, Xiaomin [2 ]
机构
[1] Weifang Univ Sci & Technol, Shandong Prov Univ Lab Protected Hort, Weifang 262700, Peoples R China
[2] Shandong Univ, Environm Res Inst, Qingdao 266200, Peoples R China
基金
中国国家自然科学基金;
关键词
noble metal; Ce0.875Zr0.125O2 (100) surface; CO oxidation; C3H6 dehydrogenation oxidation; catalytic activity; CO OXIDATION; SOOT OXIDATION; STRUCTURE SENSITIVITY; TRANSITION-METALS; CEO2(110); CEO2; DFT; NANOPARTICLES; ADSORPTION; CEO2-ZRO2;
D O I
10.3390/catal13121505
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
With the advances in engine technology, the exhaust gas temperature of automobiles has further reduced, which in turn leads to an increase in the emissions of carbon monoxide (CO) and hydrocarbons (HCs). In order to understand the influence of CeO2-based catalysts loaded with different noble metals on the catalytic oxidation activity of CO and HCs, this study constructed catalyst models of Ce0.875Zr0.125O2 (100) surfaces loaded with Pt, Pd, Ag, and Au. The electronic density and state density structures of the catalysts were analyzed, and the reaction energy barriers for CO oxidation and C3H6 dehydrogenation oxidation on the catalyst surfaces were also calculated. Furthermore, the activity sequences of the catalysts were explored. The results revealed that after loading Pt, Pd, Ag, and Au atoms onto the catalyst surfaces, these noble metal atoms exhibited strong interactions with the catalyst surfaces, and electron transfer occurred between the noble metal atoms and the catalyst surfaces. Loading with noble metals can enhance the catalytic activity of CO oxidation, but it has little effect on the dehydrogenation oxidation of C3H6. Of the different noble metals, loading with Pd exhibits the best catalytic activity for both CO and C3H6 oxidation. This study elucidated the influence of noble metal doping on the catalytic activity of catalysts at the molecular level, providing theoretical guidance for the design of a new generation of green and efficient catalysts.
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页数:11
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