Photocatalytic synthesis of alkyl-alkyl sulfones via direct C(sp3)-H bond functionalization

被引：8

作者：

Lu, Wen-Hua ^{[1
]}

Yang, Dan ^{[1
]}

Wang, Guo-Qin ^{[1
]}

Wang, Ting ^{[1
]}

Zhou, Yuan-Xia ^{[1
]}

Jing, Lin-Hai ^{[1
]}

机构：

[1] China West Normal Univ, Coll Chem & Chem Engn, Chem Synth & Pollut Control Key Lab Sichuan Prov, Nanchong 637002, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2023年 / 21卷 / 13期

关键词：

SULFUR-DIOXIDE; DECATUNGSTATE;

D O I：

10.1039/d3ob00276d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report a highly efficient one-pot, three-component strategy for the construction of alkyl-alkyl sulfones through a photoinduced TBADT-catalyzed C(sp(3))-H sulfonylation of unactivated hydrocarbon compounds. A wide range of commercially available hydrocarbon compounds and bioactive molecules can be successfully applied to the catalytic system, affording the corresponding alkyl-alkyl sulfones in good to excellent yields (>50 examples, up to 87% yield).

引用

页码：2822 / 2827

页数：6

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