Data fusion of XRF and vis-NIR using p-ComDim to predict some fertility attributes in tropical soils derived from basalt

被引:6
|
作者
dos Santos, Felipe Rodrigues [1 ,2 ]
de Oliveira, Jose Francirlei [3 ]
Bona, Evandro [4 ]
Barbosa, Graziela M. C. [3 ]
Melquiades, Fabio Luiz [1 ]
机构
[1] State Univ Londrina UEL, Appl Nucl Phys Lab, BR-86057970 Londrina, PR, Brazil
[2] Univ Sao Paulo, Ctr Nucl Energy Agr CENA, Lab Nucl Instrumentat LIN, BR-13416000 Piracicaba, SP, Brazil
[3] Rural Dev Inst Parana IDR PR, Soil Dept, BR-86047902 Londrina, PR, Brazil
[4] Fed Univ Technol Parana UTFPR, Postgrad Program Food Technol, BR-87301899 Campo Mourao, PR, Brazil
关键词
X-ray fluorescence spectroscopy; Vis-NIR spectroscopy; Data fusion; Predictive ComDim; Soil fertility; SPECTROSCOPY; COMPONENTS; REGRESSION; MODEL;
D O I
10.1016/j.microc.2023.108813
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
X-ray fluorescence (XRF) and visible and near-infrared (vis-NIR) spectroscopies have been capable of predicting soil properties. Both techniques enable environmentally friendly soil analysis with minimal or no sample preparation, providing information about inorganic and organic-mineral soil components. Recent studies have demonstrated that XRF and vis-NIR data fusion may improve the quality of predictive models for soil attributes. Although promising results have been related to the vis-NIR and XRF data fusion for soil analysis, no approach has been consistently optimal. In some cases, the data fusion worsened the models' performance compared with individual models. Moreover, most of these studies are focused on model performance. Few studies assess the synergism among different techniques and how their complementarities/differences may improve the knowledge about the sample spectral responses. For this purpose, this study aimed to assess p-ComDim analysis as a mid- level data fusion approach for soil fertility prediction using vis-NIR and XRF data. Complementarily, p-Com- Dim results were compared with vis-NIR and XRF individual models and low- and high-level data fusion ap- proaches. Soil organic carbon (SOC), exchangeable calcium (Ca2+) and magnesium (Mg2+), pH, the sum of base (SB), and cation exchange capacity (CEC) were considered representative variables of the soil chemical fertility. A relative improvement ranging from 5% to 33% was observed comparing p-ComDim with vis-NIR and XRF individual models. Moreover, p-ComDim results were better when compared with the two data fusion ap- proaches most used in literature for soil fertility prediction (low- and high-level data fusion). In addition, the p- ComDim analysis allowed extracting the weights (saliences) of each technique as well as the synergism among their variables to predict each attribute, demonstrating that the most important common dimensions (CDs) to the predictive models in all analyzed attributes were those with higher silences in the XRF block. It shows the synergism among different spectral ranges and the potential of p-ComDim for vis-NIR and XRF data fusion in soil fertility prediction. Therefore, the results from the present study may contribute to a better understanding be- tween soil sample constituents and spectral responses, assisting in the explainability of the multivariate regression models.
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收藏
页数:10
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