Ni(II) and Co(II) Acetato Complexes of Pyrazole-Pyridine Based Ligand: Synthesis, Structure and Thermal Decomposition

被引：1
|
作者：
Hopa, C. [1 ]
机构：
[1] Univ Balikesir, Fac Sci & Literature, Dept Chem, Balikesir, Turkiye
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2023年 / 64卷 / 05期
关键词：
acetato complexes; pyrazole-pyridine ligand; nickel(II); cobalt(II); single crystal; FTIR spectroscopy; thermogravimetry; crystal structure; COPPER(II) COMPLEXES; CRYSTAL-STRUCTURE; NICKEL(II); COBALT(II); CD(II);
D O I：
10.1134/S002247662305013X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel acetato complexes with NNN type planar bdmpp ligand, [Ni(OAc)(H2O)(2)(bdmpp)]OAc (1) and [Co(OAc)(H2O)(2)(bdmpp)]OAc (2) (bdmpp: 2,6-bis(3,5-dimethylpyrazolyl)pyridine) were synthesized and characterized by elemental analysis, IR spectroscopy and X-ray single-crystal diffraction analysis. Thermal stabilities of these complexes were studied by thermogravimetric and differential thermal analyses. The crystal structures of both complexes were also determined using single-crystal X-ray diffraction. It was found that complexes 1 and 2 possessed smilar octahedral coordination environment in which metal ions were coordinated by N donor atoms of bdmpp, two oxygens of aqua ligands and one oxygen atom from terminal bonding acetato ligand.
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收藏
页码：954 / 961
页数：8
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