Visible-light-induced C(sp3)-C(sp3) bond formation via radical/radical cross-coupling

被引：7
|
作者：
Li, Haoyuan [1 ]
Li, Sen [1 ]
Hu, Huimin [1 ]
Sun, Runbo [1 ]
Liu, Meixia [1 ]
Ding, Anjun [1 ]
Liu, Xiaoyong [1 ]
Luo, Wenlin [1 ]
Fu, Zhengjiang [1 ]
Guo, Shengmei [1 ]
Cai, Hu [1 ]
机构：
[1] Nanchang Univ, Dept Chem, 999 Xuefu Rd, Nanchang 330031, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 09期
关键词：
NICKEL-CATALYZED BORYLATION; BENZYLIC AMMONIUM-SALTS; C-N BONDS; ARYL; CARBOXYLATION; ALKYLATION; ESTERS;
D O I：
10.1039/d2cc05840e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Radical/radical cross-coupling remains challenging due to diffusion control issues. Herein, we report a visible-light-induced radical/radical cross-coupling reaction of quaternary ammonium salts and Hantzschs via C-N and C-C bond cleavage. The current synthetic approach furnishes 1,2-diphenylethanes in moderate to good yields and provides a method for the construction of the C(sp(3))-C(sp(3)) bond.
引用
收藏
页码：1205 / 1208
页数：4
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