Visible-light-induced C(sp3)-C(sp3) bond formation via radical/radical cross-coupling

被引：9

作者：

Li, Haoyuan ^{[1
]}

Li, Sen ^{[1
]}

Hu, Huimin ^{[1
]}

Sun, Runbo ^{[1
]}

Liu, Meixia ^{[1
]}

Ding, Anjun ^{[1
]}

Liu, Xiaoyong ^{[1
]}

Luo, Wenlin ^{[1
]}

Fu, Zhengjiang ^{[1
]}

Guo, Shengmei ^{[1
]}

Cai, Hu ^{[1
]}

机构：

[1] Nanchang Univ, Dept Chem, 999 Xuefu Rd, Nanchang 330031, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 09期

关键词：

NICKEL-CATALYZED BORYLATION; BENZYLIC AMMONIUM-SALTS; C-N BONDS; ARYL; CARBOXYLATION; ALKYLATION; ESTERS;

D O I：

10.1039/d2cc05840e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Radical/radical cross-coupling remains challenging due to diffusion control issues. Herein, we report a visible-light-induced radical/radical cross-coupling reaction of quaternary ammonium salts and Hantzschs via C-N and C-C bond cleavage. The current synthetic approach furnishes 1,2-diphenylethanes in moderate to good yields and provides a method for the construction of the C(sp(3))-C(sp(3)) bond.

引用

页码：1205 / 1208

页数：4

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