Various synthetic approaches for [6,7,m]-tricyclic compounds containing an oxygen-bridged skeleton

被引：0
作者：
Kang, Juyeon
Oh, Chang Ho [1 ,2 ]
机构：
[1] Hanyang Univ, Dept Chem, Seoul 04763, South Korea
[2] Hanyang Univ, Res Inst Nat Sci, Seoul 04763, South Korea
来源：
BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2023年 / 44卷 / 02期
基金：
新加坡国家研究基金会;
关键词：
6; 7; m]-tricyclic compound; Au catalyst; iodine; oxacyclic compound; oxygen; PLATINUM-CATALYZED CYCLIZATION; CONTAINING CARBONYL YLIDES; ELECTROPHILIC CYCLIZATION; STEREOSELECTIVE-SYNTHESIS; TANDEM; CYCLOADDITION; GENERATION; INSERTION; ACCESS;
D O I：
10.1002/bkcs.12642
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report the synthesis of [6,7,5]-tricyclic compounds containing an oxabicyclo [3.2.1] octane system from 1,6-enyne carbonyl. We also synthesized [6,7,6]-tricyclic compound from 1,7-enyne carbonyl through Au-catalyzed cyclization. The synthesis of oxacyclic compounds using iodine or oxygen is environmentally friendly cyclization methods. Oxacyclic compounds are useful for synthesizing various diterpene alkaloids.
引用
收藏
页码：163 / 167
页数：5
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