Synthesis of flexible polymer nanocomposites based on methyl cellulose/ copper oxide with desired dielectric properties for electrical applications

被引:16
作者
Abdelhamied, M. M. [1 ]
Atta, A. [2 ]
Alotaibi, B. M. [3 ]
Al-Harbi, Nuha [4 ]
Henaish, A. M. A. [5 ,6 ]
Rabia, Mohamed [7 ,8 ]
机构
[1] Egyptian Atom Energy Author EAEA, Natl Ctr Radiat Res & Technol NCRRT, Radiat Phys Dept, Charged Particles Lab, Cairo, Egypt
[2] Jouf Univ, Coll Sci, Phys Dept, POB 2014, Sakaka, Saudi Arabia
[3] Princess Nourah Bint Abdulrahman Univ, Coll Sci, Phys Dept, POB 84428, Riyadh 11671, Saudi Arabia
[4] Umm Al Qura Univ, Fac Appl Sci, Dept Phys, Mecca, Saudi Arabia
[5] Ural Fed Univ, NANOTECH Ctr, Ekaterinburg 620002, Russia
[6] Tanta Univ, Fac Sci, Phys Dept, Tanta 31527, Egypt
[7] Beni Suef Univ, Fac Sci, Chem Dept, Nanomat Sci Res Lab, Bani Suwayf 62514, Egypt
[8] Beni Suef Univ, Fac Sci, Phys Dept, Nanophoton & Applicat Lab, Bani Suwayf 62514, Egypt
关键词
Polymer nanocomposite; Structural; Surface morphology; Dielectric properties; POLYVINYL-ALCOHOL; NANOPARTICLES; CONDUCTIVITY; POLYANILINE;
D O I
10.1016/j.inoche.2023.111245
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Herein, flexible MC/CuO composite consisting of methyl cellulose (MC) and copper oxide (CuO) were successfully fabricated by casting solution technique. The synthesized films were characterized by XRD, FTIR, and EDX methods, which confirm the successful preparation of the composite MC/CuO. Moreover, SEM images are investigated homogenous distribution of CuO in MC. The modulus, conductivity, and impedance of MC and CuO films were measured in frequency 50 Hz to 5 x 105 Hz. The addition of CuONPs to MC films induces a significant improvement in the permittivity due to the high level of scission. The conductivity is raised from 0.08 x 10-6 S/ cm for MC to 6.77 x 10-6 S/cm for MC/9%CuO, and the dielectric constant raised from 6.32 to 70.6 at frequency of 100 Hz. The energy density is increased for MC from 2.79 x 10-5 J/m3 to 18.5 x 10-5 J/m3 and to 31.2 x 10-5 J/m3 by enhancing CuO content from 3% to 9% respectively. The barrier potential energy Wm was lowered from 0.58 eV for MC to 0.38 eV and to 0.36 eV after the increases CuO content from 3% to 9%. This results confirmed an improvement in the characteristics of MC/CuO films to be applied these films in a variety of industrial devices, including batteries and super-capacitors.
引用
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页数:9
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