Photocatalytic chemo-, regio- & stereoselective olefinic β-C-H decarboxylative alkylation of enamides with diacyl peroxides

被引：12

作者：

Liu, Han ^{[1
]}

Wu, Yechun ^{[1
]}

Liu, Lingli ^{[1
]}

Yu, Jin-Tao ^{[1
]}

Pan, Changduo ^{[1
,2
]}

机构：

[1] Changzhou Univ, Sch Petrochem Engn, Changzhou 213164, Peoples R China

[2] Jiangsu Univ Technol, Sch Chem & Chem Engn, Changzhou 213001, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 55期

基金：

中国国家自然科学基金;

关键词：

C(SP(2))-H ARYLSULFONYLATION; UNACTIVATED ALKENES; ACID ANHYDRIDES; SULFUR-DIOXIDE; FUNCTIONALIZATION; VINYLARENES; BONDS; ALKYNYLATION; OLEFINATION; ACYLATION;

D O I：

10.1039/d3cc01908j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A decarboxylative alkylation of enamides with alkyl diacyl peroxides induced by visible-light is described. The chemo-, regio- and stereoselective olefinic beta-C-H alkylation generates a series of primary- and secondary alkylated enamides in yields up to 95%. This transformation bears the advantages of operational simplicity, good functional group compatibility and mild conditions.

引用

页码：8556 / 8559

页数：4

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