Photocatalytic chemo-, regio- & stereoselective olefinic β-C-H decarboxylative alkylation of enamides with diacyl peroxides

被引：12
作者：
Liu, Han [1 ]
Wu, Yechun [1 ]
Liu, Lingli [1 ]
Yu, Jin-Tao [1 ]
Pan, Changduo [1 ,2 ]
机构：
[1] Changzhou Univ, Sch Petrochem Engn, Changzhou 213164, Peoples R China
[2] Jiangsu Univ Technol, Sch Chem & Chem Engn, Changzhou 213001, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 55期
基金：
中国国家自然科学基金;
关键词：
C(SP(2))-H ARYLSULFONYLATION; UNACTIVATED ALKENES; ACID ANHYDRIDES; SULFUR-DIOXIDE; FUNCTIONALIZATION; VINYLARENES; BONDS; ALKYNYLATION; OLEFINATION; ACYLATION;
D O I：
10.1039/d3cc01908j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A decarboxylative alkylation of enamides with alkyl diacyl peroxides induced by visible-light is described. The chemo-, regio- and stereoselective olefinic beta-C-H alkylation generates a series of primary- and secondary alkylated enamides in yields up to 95%. This transformation bears the advantages of operational simplicity, good functional group compatibility and mild conditions.
引用
收藏
页码：8556 / 8559
页数：4
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