A novel azo compound derived from ethyl-4-amino benzoate: synthesis, nonlinear optical properties and DFT investigations

被引:5
作者
Hassan, Qusay M. A. [1 ]
Al-Asadi, Rafid H. [1 ,2 ]
Sultan, H. A. [1 ]
Abdullmajed, Hasanain A. [2 ]
Ali, Asaad A. [2 ]
Emshary, C. A. [1 ]
机构
[1] Univ Basrah, Coll Educ Pure Sci, Dept Phys, Basrah 61001, Iraq
[2] Univ Basrah, Coll Educ Pure Sci, Dept Chem, Basrah 61001, Iraq
关键词
Novel azo dye; DFT; DPs; Z-scan; All-optical switching; SELF-PHASE MODULATION; DIFFRACTION RINGS; Z-SCAN; COMPLEXES; FILMS; DYES;
D O I
10.1007/s11082-023-04660-9
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
A novel azo dye compound, Ethyl (E)-4-((5-hydroxy-3,4-bis(hydroxyl methyl)-6-methyl. pyridin-2-yl)diazenyl)benzoate (EAB), have been synthesized by the coupling reaction and characterized by FT-IR, H-1-and C-13-NMR, Mass, and UV-visible spectroscopies. The nonlinear optical (NLO) properties of the EAB compound via the finding of the nonlinear refractive index (NRI) using continuous wave (cw), low power 473 nm, TEM00 mode laser beam have been studied via the diffraction patterns (DPs) and the Z-scan. Effect of power input of the laser beam, types of beam wavefront and temporal variation of the DPs are discussed. The all-optical switching (AOS) using two laser beams is proved to occur in this compound.
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页数:18
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