Clusters of Fe-Co-Cd nanosheets grow on the surface of nickel foam to enhance the oxygen evolution reaction

被引:3
作者
Tian, Yixin [1 ]
Tao, Yuting [1 ]
Huang, Changzhu [1 ]
Geng, Xue [1 ]
Gong, Chen [3 ]
Wang, Zhongyu [1 ]
Hu, Chen [2 ]
Ou, Mingze [2 ]
Lin, Jia [1 ,4 ]
Wu, Jiang [2 ,4 ]
Peng, Lin [1 ]
You, Chang [2 ]
Yu, Zixiao [2 ]
机构
[1] Shanghai Univ Elect Power, Coll Math & Phys, Shanghai 200090, Peoples R China
[2] Shanghai Univ Elect Power, Coll Energy & Mech Engn, Shanghai 200090, Peoples R China
[3] Sun Yat Sen Univ, Sch Environm Sci & Engn, Guangzhou 510006, Peoples R China
[4] 2103 Pingliang Rd, Shanghai 200090, Peoples R China
基金
中国国家自然科学基金;
关键词
Synergistic effect; Composite material; Oxygen evolution reaction; Electrocatalyst; HYDROGEN; PERFORMANCE;
D O I
10.1016/j.jpcs.2023.111660
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
To enhance the efficiency of water electrolysis for hydrogen energy production, it is essential to synthesize oxygen evolution reaction (OER) catalysts that are both high-performing and low-cost. In this study, a self-supporting electrocatalyst denoted as was synthesized using the hydrothermal method by growing trimetallic nanosheets FeCoCd@C in situ on nickel foam. This electrocatalyst is composed of transition metal hydroxides and carbon materials, which exhibit a specific interaction between them. The electrocatalyst demonstrates outstanding OER performance, achieving a current density of 10 mA cm-2 in a 1.0 M KOH electrolyte with only 216 mV overpotential and a Tafel slope of 75.86 mV dec-1. Furthermore, carbon materials can prevent direct contact between the electrolyte and transition metal hydroxide, effectively impeding electrocatalyst corrosion, and providing long-term stability. Additionally, a comprehensive analysis of the physical and chemical properties of the composite catalyst was carried out to elucidate its mechanism of action. This study confirms that the combination of transition metal hydroxides and carbon materials can effectively enhance the catalytic activity of electrocatalysts, providing a clear direction for the development of composite OER catalysts.
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页数:7
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