Clusters of Fe-Co-Cd nanosheets grow on the surface of nickel foam to enhance the oxygen evolution reaction

被引:3
作者
Tian, Yixin [1 ]
Tao, Yuting [1 ]
Huang, Changzhu [1 ]
Geng, Xue [1 ]
Gong, Chen [3 ]
Wang, Zhongyu [1 ]
Hu, Chen [2 ]
Ou, Mingze [2 ]
Lin, Jia [1 ,4 ]
Wu, Jiang [2 ,4 ]
Peng, Lin [1 ]
You, Chang [2 ]
Yu, Zixiao [2 ]
机构
[1] Shanghai Univ Elect Power, Coll Math & Phys, Shanghai 200090, Peoples R China
[2] Shanghai Univ Elect Power, Coll Energy & Mech Engn, Shanghai 200090, Peoples R China
[3] Sun Yat Sen Univ, Sch Environm Sci & Engn, Guangzhou 510006, Peoples R China
[4] 2103 Pingliang Rd, Shanghai 200090, Peoples R China
基金
中国国家自然科学基金;
关键词
Synergistic effect; Composite material; Oxygen evolution reaction; Electrocatalyst; HYDROGEN; PERFORMANCE;
D O I
10.1016/j.jpcs.2023.111660
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
To enhance the efficiency of water electrolysis for hydrogen energy production, it is essential to synthesize oxygen evolution reaction (OER) catalysts that are both high-performing and low-cost. In this study, a self-supporting electrocatalyst denoted as was synthesized using the hydrothermal method by growing trimetallic nanosheets FeCoCd@C in situ on nickel foam. This electrocatalyst is composed of transition metal hydroxides and carbon materials, which exhibit a specific interaction between them. The electrocatalyst demonstrates outstanding OER performance, achieving a current density of 10 mA cm-2 in a 1.0 M KOH electrolyte with only 216 mV overpotential and a Tafel slope of 75.86 mV dec-1. Furthermore, carbon materials can prevent direct contact between the electrolyte and transition metal hydroxide, effectively impeding electrocatalyst corrosion, and providing long-term stability. Additionally, a comprehensive analysis of the physical and chemical properties of the composite catalyst was carried out to elucidate its mechanism of action. This study confirms that the combination of transition metal hydroxides and carbon materials can effectively enhance the catalytic activity of electrocatalysts, providing a clear direction for the development of composite OER catalysts.
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页数:7
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共 52 条
  • [1] Synthesis of emerging two-dimensional (2D) materials-Advances, challenges and prospects
    Alam, Shahinoor
    Chowdhury, Mohammad Asaduzzaman
    Shahid, Abdus
    Alam, Rubel
    Rahim, Abdur
    [J]. FLATCHEM, 2021, 30
  • [2] Electronic structure engineering for electrochemical water oxidation
    Babar, Pravin
    Mahmood, Javeed
    Maligal-Ganesh, Raghu, V
    Kim, Seok-Jin
    Xue, Zhonghua
    Yavuz, Cafer T.
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2022, 10 (38) : 20218 - 20241
  • [3] Low-overpotential overall water splitting by a cooperative interface of cobalt-iron hydroxide and iron oxyhydroxide
    Babar, Pravin
    Patil, Komal
    Mahmood, Javeed
    Kim, Seok-jin
    Kim, Jin Hyeok
    Yavuz, Cafer T.
    [J]. CELL REPORTS PHYSICAL SCIENCE, 2022, 3 (02):
  • [4] Constructing 3D Bi/Bi4O5I2 microspheres with rich oxygen vacancies by one-pot solvothermal method for enhancing photocatalytic activity on mercury removal
    Chen, Liping
    Li, Chaoen
    Zhao, Yanfeng
    Wu, Jiang
    Li, Xiaokun
    Qiao, Zhanwei
    He, Ping
    Qi, Xuemei
    Liu, Zhenhao
    Wei, Guoqing
    [J]. CHEMICAL ENGINEERING JOURNAL, 2021, 425
  • [5] Design of earth-abundant amorphous transition metal-based catalysts for electrooxidation of small molecules: Advances and perspectives
    Chen, Zhijie
    Han, Ning
    Zheng, Renji
    Ren, Zijie
    Wei, Wei
    Ni, Bing-Jie
    [J]. SUSMAT, 2023, 3 (03): : 290 - 319
  • [6] Waste-Derived Catalysts for Water Electrolysis: Circular Economy-Driven Sustainable Green Hydrogen Energy
    Chen, Zhijie
    Yun, Sining
    Wu, Lan
    Zhang, Jiaqi
    Shi, Xingdong
    Wei, Wei
    Liu, Yiwen
    Zheng, Renji
    Han, Ning
    Ni, Bing-Jie
    [J]. NANO-MICRO LETTERS, 2023, 15 (01)
  • [7] Dual-anion etching induced in situ interfacial engineering for high-efficiency oxygen evolution
    Chen, Zhijie
    Zheng, Renji
    Li, Shangying
    Wang, Ranhao
    Wei, Wenfei
    Wei, Wei
    Ni, Bing-Jie
    Chen, Hong
    [J]. CHEMICAL ENGINEERING JOURNAL, 2022, 431
  • [8] Integrating high-efficiency oxygen evolution catalysts featuring accelerated surface reconstruction from waste printed circuit boards via a boriding recycling strategy
    Chen, Zhijie
    Zheng, Renji
    Zou, Wensong
    Wei, Wenfei
    Li, Jing
    Wei, Wei
    Ni, Bing-Jie
    Chen, Hong
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2021, 298
  • [9] Synergistic recycling and conversion of spent Li-ion battery leachate into highly efficient oxygen evolution catalysts
    Chen, Zhijie
    Zou, Wensong
    Zheng, Renji
    Wei, Wenfei
    Wei, Wei
    Ni, Bing-Jie
    Chen, Hong
    [J]. GREEN CHEMISTRY, 2021, 23 (17) : 6538 - 6547
  • [10] The electrolysis of water
    de Levie, R
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 476 (01): : 92 - 93