Recent Advances in Dual Triplet Ketone/Transition-Metal Catalysis

被引：9
|
作者：
Iziumchenko, Valeriia [1 ]
Gevorgyan, Vladimir [1 ]
机构：
[1] Univ Texas Dallas, Dept Chem & Biochem, Richardson, TX 75080 USA
来源：
SYNLETT | 2023年 / 34卷 / 12期
基金：
美国国家卫生研究院; 美国国家科学基金会;
关键词：
dual catalysis; triplet ketone; transition-metal catalysis; photocatalysis; photosensitizer; C-H functionalization; C-H BONDS; HIGHLY EFFICIENT; C(SP(3))-H BONDS; TERTIARY-AMINES; PHOTOCATALYSIS; CARBOXYLATION; BENZOPHENONE; ALKENES; ENABLES; KETONES;
D O I：
10.1055/s-0042-1751444
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Dual light-excited ketone/transition-metal catalysis is a rapidly developing field of photochemistry. It allows for versatile functionalizations of C-H or C-X bonds enabled by triplet ketone acting as a hydrogen-atom-abstracting agent, a single-electron acceptor, or a photosensitizer. This review summarizes recent developments of synthetically useful transformations promoted by the synergy between triplet ketone and transition-metal catalysis.1 Introduction2 Triplet Ketone Catalysis via Hydrogen Atom Transfer2.1 Triplet Ketones with Nickel Catalysis2.2 Triplet Ketones with Copper Catalysis2.3 Triplet Ketones with Other Transition-Metal Catalysis3 Triplet Ketone Catalysis via Single-Electron Transfer4 Triplet Ketone Catalysis via Energy Transfer5 Conclusions
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页码：1289 / 1308
页数：20
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