A DyIII single-ion magnet with D5h configuration

被引：1
作者：
Chen, Chun-Pu [1 ]
Wang, Yu-Feng [1 ]
Qin, Pei [1 ]
Zou, Hua-Hong [1 ]
Liang, Fu-Pei [1 ,2 ]
机构：
[1] Guangxi Normal Univ, Sch Chem & Pharmaceut Sci, State Key Lab Chem & Mol Engn Med Resources, Guilin 541004, Peoples R China
[2] Guilin Univ Technol, Coll Chem & Bioengn, Guangxi Key Lab Electrochem & Magnetochem Funct Ma, Guilin 541004, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2023年 / 547卷
基金：
中国国家自然科学基金;
关键词：
Lanthanoid coordinate cluster; Pentagonal bipyramidal; Single-Ion Magnet; Schiff base; Slow relaxation process; DY-III; LN(III) COMPLEXES; MOLECULE MAGNETS; ENERGY BARRIERS; ANISOTROPY; SPIN; MAGNETIZATION; RELAXATION; BEHAVIOR; STRATEGIES;
D O I：
10.1016/j.ica.2022.121343
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A DyIII single-ion magnet [Dy(L1)(L2)] (1, HL1 = (E)-2-(((3-aminopropyl)imino)methyl) phenol, H2L2 = 2,2 '- ((1E,1 ' E)-(propane-1,3-diylbis(azaneylylidene))bis(methaneylylidene))diphenol) was synthesized by self -assembly of dysprosium nitrate hexahydrate, 1,3-diaminopropane and salicylaldehyde under solvothermal method. As far as we know, complex 1 synthesized in this work is the highest Ueff of pentagonal bipyramidal with four neutral nitrogen atoms and one oxygen anion occupying the equatorial plane, while the axis is occupied by two oxygen atoms, in DyIII single-molecule magnets. Magnetic characterizations reveal that complex 1 exhibit slow magnetic relaxation behavior with Ueff = 95.98 K and tau 0 = 8.76 x 10-7 s.
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页数：6
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