Thermal decomposition of flexible polyurethane foam under nitrogen and air atmospheres: Thermogravimetric analysis by ETp method

被引：5
作者：
Zhu, Hong [1 ,2 ]
Wang, Zhenzhen [1 ,2 ]
Liu, Naian [1 ,2 ]
Gao, Wei [1 ,2 ]
Xie, Xiaodong [1 ,2 ]
Huang, Mengzhen [1 ,2 ]
机构：
[1] Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230027, Anhui, Peoples R China
[2] Univ Sci & Technol China, MEM Key Lab Forest Fire Monitoring & Warning, Hefei 230027, Anhui, Peoples R China
来源：
THERMOCHIMICA ACTA | 2023年 / 727卷
基金：
中国博士后科学基金;
关键词：
Kinetic analysis; Model -fitting method; Flexible polyurethane foam; Thermal decomposition; KINETICS; DEGRADATION; PYROLYSIS; ALGORITHM; MECHANISM; RELEASE; SEARCH;
D O I：
10.1016/j.tca.2023.179572
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The thermal decomposition of flexible polyurethane foam (FPUF) is investigated by thermogravimetric (TG) analysis with dynamic runs at four heating rates (5, 10, 15, and 20 & DEG;C min-1) under nitrogen and air atmo-spheres. A reaction scheme consisting of six competitive and consecutive reactions is proposed for thermal decomposition of FPUF. The results show that the reaction scheme fits all the experimental data in this work. The kinetic parameters are extracted by model-fitting methods, based on the shuffled complex evolution (SCE) al-gorithm, and Gpyro software. The model-fitting methods are the EA method and the ETp method (Zhu and Liu, Thermochimica Acta, 690, 2020). This work is the first effort to analyze polymer thermal decomposition using the ETp method. The outstanding performance of the ETp-SCE method is confirmed via comparison with the EA -SCE method. The results show that the ETp method is applicable for polymer, oxidizing atmosphere, competitive reaction, consecutive reaction, SCE algorithm, and Gpyro software.
引用
收藏
页数：9
相关论文
共 34 条
[1]   Kinetics of the thermal decomposition of polyurethane foams in nitrogen and air atmospheres [J].
Bilbao, R ;
Mastral, JF ;
Ceamanos, J ;
Aldea, ME .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1996, 37 (01) :69-82
[2]   Comparison of the thermal decomposition behavior of a non-fire retarded and a fire retarded flexible polyurethane foam with phosphorus and brominated additives [J].
Chao, CYH ;
Wang, JH .
JOURNAL OF FIRE SCIENCES, 2001, 19 (02) :137-156
[3]   Thermal Analysis and Decomposition Kinetics of Chinese Forest Peat under Nitrogen and Air Atmospheres [J].
Chen, Haixiang ;
Zhao, Weitao ;
Liu, Naian .
ENERGY & FUELS, 2011, 25 (02) :797-803
[4]   Application of the global search algorithm to analyze the kinetic mechanism of the thermal decomposition of flexible polyurethane foam [J].
Chen, Yangui ;
He, Hongzhou ;
Liu, Zhongqing .
PROGRESS IN REACTION KINETICS AND MECHANISM, 2021, 46 :1-18
[5]   Mechanisms controlling the degradation of poly(methyl methacrylate) prior to piloted ignition [J].
Dakka, SM ;
Jackson, GS ;
Torer, JL .
PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2002, 29 (01) :281-287
[6]   DEGRADATION OF CONTAMINATED PLASTICS - A KINETIC-STUDY [J].
DAY, M ;
COONEY, JD ;
MACKINNON, M .
POLYMER DEGRADATION AND STABILITY, 1995, 48 (03) :341-349
[7]   Numerical examination of two-dimensional smolder structure in polyurethane foam [J].
Dodd, A. B. ;
Lautenberger, C. ;
Fernandez-Pello, A. C. .
PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2009, 32 :2497-2504
[8]   Friedman and n-reaction order methods applied to pine needles and polyurethane thermal decompositions [J].
Font, R. ;
Garrido, M. A. .
THERMOCHIMICA ACTA, 2018, 660 :124-133
[9]   Pyrolysis and combustion study of flexible polyurethane foam [J].
Garrido, M. A. ;
Font, R. .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2015, 113 :202-215
[10]   Composite auto-ignition criterion for PMMA (Poly methyl methacrylate) exposed to linearly declining thermal radiation [J].
Gong, Junhui ;
Zhang, Mingrui ;
Zhai, Chunjie .
APPLIED THERMAL ENGINEERING, 2021, 195
1234