Alcohol solvent effect on the self-assembly behaviors of lignin oligomers

被引:6
作者
Ma, Ya [1 ,2 ]
Jiang, Zhicheng [1 ,2 ]
Luo, Yafei [3 ]
Guo, Xingjie [1 ,2 ]
Liu, Xudong [4 ]
Luo, Yiping [5 ]
Shi, Bi [1 ,2 ]
机构
[1] Sichuan Univ, Coll Biomass Sci & Engn, Chengdu 610065, Peoples R China
[2] Sichuan Univ, Natl Engn Res Ctr Clean Technol Leather Ind, Chengdu 610065, Peoples R China
[3] Chongqing Univ Arts & Sci, Int Acad Targeted Therapeut & Innovat, Coll Pharm, Chongqing 402160, Peoples R China
[4] Hunan Acad Forestry, State Key Lab Utilizat Woody Oil Resource, Changsha 410004, Peoples R China
[5] Chinese Acad Sci, Chengdu Inst Biol, CAS Key Lab Environm & Appl Microbiol, Environm Microbiol Key Lab Sichuan Prov, Chengdu 610041, Peoples R China
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
Lignin oligomers; Alcohol solvent; Self-assembly; LNPs; Solvent effects; NANOPARTICLES; SIZE;
D O I
10.1016/j.gee.2023.05.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The interactions between lignin oligomers and solvents determine the behaviors of lignin oligomers self-assembling into uniform lignin nanoparticles (LNPs). Herein, several alcohol solvents, which readily interact with the lignin oligomers, were adopted to study their effects during solvent shifting process for LNPs' production. The lignin oligomers with widely distributed molecular weight and abundant guaiacyl units were extracted from wood waste (mainly consists of pine wood), exerting outstanding self-assembly capability. Uniform and spherical LNPs were generated in H2O-n-propanol cosolvent, whereas irregular LNPs were obtained in H2O-methanol cosolvent. The unsatisfactory selfassembly performance of the lignin oligomers in H2O-methanol cosolvent could be attributed to two aspects. On one hand, for the initial dissolution state, the distinguishing Hansen solubility parameter and polarity between methanol solvent and lignin oligomers resulted in the poor dispersion of the lignin oligomers. On the other hand, strong hydrogen bonds between methanol solvent and lignin oligomers during solvent shifting process, hindered the interactions among the lignin oligomers for self-assembly. (c) 2023 Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co., Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
引用
收藏
页码:597 / 603
页数:7
相关论文
共 36 条
  • [1] Synthesis of pH-Responsive Lignin-Based Nanocapsules for Controlled Release of Hydrophobic Molecules
    Chen, Nusheng
    Dempere, Luisa Amelia
    Tong, Zhaohui
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2016, 4 (10): : 5204 - 5211
  • [2] Dean J.A, 1999, Lange' Handbook of Chemistry, Vfifteenth
  • [3] Structural Characterization of Wheat Straw Lignin as Revealed by Analytical Pyrolysis, 2D-NMR, and Reductive Cleavage Methods
    del Rio, Jose C.
    Rencoret, Jorge
    Prinsen, Pepijn
    Martinez, Angel T.
    Ralph, John
    Gutierrez, Ana
    [J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2012, 60 (23) : 5922 - 5935
  • [4] Structural Characterization of Guaiacyl-rich Lignins in Flax (Linum usitatissimum) Fibers and Shives
    del Rio, Jose C.
    Rencoret, Jorge
    Gutierrez, Ana
    Nieto, Lidia
    Jimenez-Barbero, Jesus
    Martinez, Angel T.
    [J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2011, 59 (20) : 11088 - 11099
  • [5] Catalytic conversion of lignocellulosic biomass into chemicals and fuels
    Deng, Weiping
    Feng, Yunchao
    Fu, Jie
    Guo, Haiwei
    Guo, Yong
    Han, Buxing
    Jiang, Zhicheng
    Kong, Lingzhao
    Li, Changzhi
    Liu, Haichao
    Nguyen, Phuc T. T.
    Ren, Puning
    Wang, Feng
    Wang, Shuai
    Wang, Yanqin
    Wang, Ye
    Wong, Sie Shing
    Yan, Kai
    Yan, Ning
    Yang, Xiaofei
    Zhang, Yuanbao
    Zhang, Zhanrong
    Zeng, Xianhai
    Zhou, Hui
    [J]. GREEN ENERGY & ENVIRONMENT, 2023, 8 (01) : 10 - 114
  • [6] Fabrication of uniform lignin nanoparticles with tunable size for potential wound healing application
    Du, Boyu
    Li, Wanjing
    Bai, Yating
    Pan, Zheng
    Wang, Qingyu
    Wang, Xing
    Ding, Hui
    Lv, Gaojin
    Zhou, Jinghui
    [J]. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2022, 214 : 170 - 180
  • [7] Solubility parameters for determining optimal solvents for separating PVC from PVC-coated PET fibers
    Grause, Guido
    Hirahashi, Suguru
    Toyoda, Hiroshi
    Kameda, Tomohito
    Yoshioka, Toshiaki
    [J]. JOURNAL OF MATERIAL CYCLES AND WASTE MANAGEMENT, 2017, 19 (02) : 612 - 622
  • [8] The ultrastructure of wood from a solubility parameter point of view
    Hansen, CM
    Bjorkman, A
    [J]. HOLZFORSCHUNG, 1998, 52 (04) : 335 - 344
  • [9] Synthesis of Au/lignin-tannin particles and their anticancer application
    Jiang, Zhicheng
    Duan, Jinjie
    Guo, Xingjie
    Ma, Ya
    Wang, Chunjiong
    Shi, Bi
    [J]. GREEN CHEMISTRY, 2021, 23 (18) : 6945 - 6952
  • [10] Sustainable production of lignin micro-/nano-particles (LMNPs) from biomass: Influence of the type of biomass on their self-assembly capability and physicochemical properties
    Jiang, Zhicheng
    Ma, Ya
    Guo, Xingjie
    Remon, Javier
    Tsang, Daniel C. W.
    Hu, Changwei
    Shi, Bi
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2021, 403