Self-supporting CuM LDH (M = Ni, Fe, Co) carbon cloth electrodes for selective electrochemical ammonia oxidation to nitrogen

被引：12

作者：

Cui, Jing ^{[1
]}

Hou, Jing ^{[1
]}

Pan, Hui ^{[1
]}

Kang, Peng ^{[1
]}

机构：

[1] Tianjin Univ, Sch Chem Engn & Technol, 135 Yaguan Rd, Tianjin 300350, Peoples R China

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2023年 / 940卷

关键词：

Ammonia oxidation; Electrocatalysts; CuCo; CC electrode; ELECTROOXIDATION;

D O I：

10.1016/j.jelechem.2023.117502

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Electrochemical ammonia oxidation reaction (eAOR) has important applications in ammonia fuel cells and wastewater treatment due to its environmental friendliness and convenient operation. In this study, hydrothermal synthesis was used to create self-supported CuM (M = Ni, Fe, Co) carbon cloth electrodes. After three hours of electrolysis at 1.65 V vs. RHE, a CuCo/CC electrode with the ideal Cu/Co ratio (1:2) achieved the maximum dinitrogen selectivity of 90.0% and Faraday efficiency of 77.4%. The reaction mechanism was investigated using Raman and in-situ IR spectroscopy. Cu serves as NH3 adsorption sites and Co catalyzes the oxidation, and together achieve high efficiency.

引用

页数：8

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