Improvement the near-infrared luminescence properties of double perovskite phosphor La(Mg0.5Sn0.5In0.5Sc0.5)0.5O3:Cr3+via co-doping Yb3+

被引:5
作者
Li, Jingxin [1 ]
Zhang, WenYan [2 ]
Wang, XueFang [2 ]
Peng, RunQiu [2 ]
Gao, BingKai [2 ]
Wu, Qian [2 ]
Zhang, Zicai [2 ]
Wang, Zhijun [2 ]
机构
[1] Hebei Univ, Coll Publ Hlth, Baoding 071002, Peoples R China
[2] Hebei Univ, Coll Phys Sci & Technol, Hebei Key Lab Opt Elect Informat & Mat, Baoding 071002, Peoples R China
基金
中国国家自然科学基金;
关键词
Luminescence; Phosphor; Energy transfer; ENERGY-TRANSFER;
D O I
10.1016/j.ceramint.2022.10.139
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In recent years, the broadband near-infrared (NIR) spectroscopy technology has been widely used in the field of nondestructive testing. However, these existing NIR phosphors showed relatively short emission wavelengths, narrower half-maximum full-width (FWHM), and narrower half-peak widths, importantly, few phosphors pre-sented the emission from 950 nm to 1100 nm. In order to solve these problems, the Yb3+/Cr3+ ions codoped La (Mg0.5Sn0.5In0.5Sc0.5)0.5O3 (LMSIS) was synthesized by the solid-state method, and the emission spectrum of LMSIS:Cr3+ can be extended to the NIR long-wave region due to the energy transfer of Yb3+ and Cr3+, and the thermal stability of the phosphor can be improved due to the inherent temperature stability of the Yb3+ f-f transition. The NIR phosphor converted light emitting diodes (pc-LEDs) were fabricated by combining the LMSIS:0.003Cr3+, 0.0015Yb3+ with blue LED chip, which can be expected to be used in the field of broadband near-infrared non-destructive detection.
引用
收藏
页码:6246 / 6253
页数:8
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