A novel strategy for the design of cooperatively reinforced, shape-memory, recyclable ESO-based carbon fiber composites

被引:4
作者
Gong, Yuning [1 ]
Liu, Yu [1 ]
Zhu, Chengshuang [2 ]
Qi, Zhijie [1 ]
Zhang, Chunhong [1 ]
Li, Ming [1 ]
Wang, Lu [1 ]
Yan, Zihan [1 ]
Shang, Lei [1 ]
Ao, Yuhui [1 ]
机构
[1] Changchun Univ Technol, Coll Chem & Life Sci, Jilin Prov Key Lab Carbon Fiber Dev & Applicat, Changchun 130012, Peoples R China
[2] Changchun Zhiyuan New Energy Equipment Co Ltd, Changchun, Jilin, Peoples R China
关键词
Carbon fiber composite; Bio-base epoxy resins; Recycling; Shape-memory; BISPHENOL-A; THERMOSETS;
D O I
10.1016/j.indcrop.2023.117984
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
To improve the poor performance of epoxidized soybean oil (ESO) thermosetting materials in preparing highperformance carbon fiber composites, we synthesized novel bio-based epoxy monomers using naringin (EN) as an epoxy monomer. EN's hydrogen bonding and benzopyrenone structure enhanced the crosslinking density, rigidity, bond shear strength, glass transition temperature (Tg), tensile and lap shear strength, and shape memory ability of ESO/MeHHPA/EN. The resulting carbon fiber composites had high tensile strength (349 MPa) and could be fully recovered using ethanolamine, with the recovered fibers maintaining almost 100% of the mechanical properties of the original sample. This study provides a new approach for fabricating multifunctional, high-performance, and recyclable ESO-based carbon fiber reinforced composites.
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页数:11
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