Photo-Induced Cleavage of Alkenes to Carbonyls in Water

被引：4

作者：

Yue, Xiaoguang ^{[1
]}

Ouyang, Yani ^{[1
]}

Zhu, Jiashun ^{[1
]}

Yue, Jingfang ^{[1
]}

Peng, Jiehai ^{[1
]}

Li, Wanmei ^{[1
]}

机构：

[1] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Peoples R China

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 12卷 / 06期

关键词：

Oxidative cleavage of alkenes; Photocatalytic oxidation; Charge-transfer complexes; Aldehydes; Ketones; GEM-DISUBSTITUTED ALKENES; OXIDATIVE CLEAVAGE; SELECTIVE OXIDATION; MOLECULAR-OXYGEN; LIGHT; ALDEHYDES; OLEFINS; ACTIVATION; EFFICIENT; ADDITIONS;

D O I：

10.1002/ajoc.202300124

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A method of the oxidative cracking of olefins' C=C bonds promoted by NaN3 in water without photocatalyst was developed. Some typical cheap olefins could be converted to aldehydes or ketones in moderate to good yields at room temperature under blue light irradiation. The experimental results showed that NaN3-O-2 charge-transfer complexes might be formed during the reaction, and then oxidized and cracked, finally formed aldehydes or ketones.

引用

页数：5

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