Microstructures evolution and chloride migration characteristics of concrete under ultra-deep underground environment

被引:40
作者
Chen, Yong-qing [1 ,2 ,3 ]
Ma, Xiong-ying [1 ,2 ,3 ]
Tong, Xin-yang [1 ,2 ,3 ]
Kang, Xin [1 ,2 ,3 ]
机构
[1] Hunan Univ, Key Lab Bldg Safety & Energy Efficiency, Minist Educ, Changsha 410082, Peoples R China
[2] Hunan Univ, Natl Ctr Int Res Collaborat Bldg Safety & Environm, Changsha 410082, Peoples R China
[3] Hunan Univ, Coll Civil Engn, Changsha 410082, Peoples R China
关键词
Ultra-deep buried concrete; Ca leaching; Micro-nano pores; Cracks propagation; Chloride attack; Bound chloride; CEMENT-BASED MATERIALS; C-S-H; DC STRAY CURRENT; BOUND CHLORIDE; BINDING; MECHANISMS; CORROSION; INCREASE; CRACKING; MODULUS;
D O I
10.1016/j.cemconcomp.2023.104936
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
Understanding the microstructures evolution and chloride migration characteristics of concrete is essential to solve the durability problem of reinforced concrete structures in ultra-deep buried rail transit projects (40 m-100 m). Herein, we developed a novel experimental system that can simulate the corrosion process under high hydraulic pressure and stray current coexistence environment. The changes in microstructures, phases, elements, minerals, and the Ca-leaching were comprehensively investigated. Further, the mechanisms of pores and cracks propagation, and migration characteristics of chloride ions were revealed. The results showed that stray current and hydraulic pressure significantly altered the microstructures of concrete, both of which led to the increase of specific surface area, porosity, pore diameter and more ink-bottle-shaped pores. The development of dominant microfractures and three types of crack propagation patterns caused by hydraulic pressure were found, and the mechanical framework for "local fracturing" was established. Migration characteristics in micro-nano scale showed chloride ions were mainly transported along the pores, and the decrease of adsorption sites was the main reason.
引用
收藏
页数:21
相关论文
共 61 条
[1]   Nanomechanical and Surface Morphological Properties of Hydrated Cement Paste Containing Volcanic Ash and Micro-or Nano-Silica [J].
Al-Bahar, S. ;
Chakkamalayath, J. ;
Joseph, A. ;
Al-Otaibi, S. ;
Abdulsalam, M. .
KSCE JOURNAL OF CIVIL ENGINEERING, 2018, 22 (04) :1354-1360
[3]  
[Anonymous], 2013, JGJT 322-2013
[4]  
[Anonymous], 2009, GB/T 50082-2009
[5]   Prediction of chloride binding isotherms of cementitious materials by analytical model or numerical inverse analysis [J].
Baroghel-Bouny, V. ;
Wang, X. ;
Thiery, M. ;
Saillio, M. ;
Barberon, F. .
CEMENT AND CONCRETE RESEARCH, 2012, 42 (09) :1207-1224
[6]   THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS [J].
BARRETT, EP ;
JOYNER, LG ;
HALENDA, PP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :373-380
[7]   Modeling of the influence of transverse cracking on chloride penetration into concrete [J].
Bentz, Dale P. ;
Garboczi, Edward J. ;
Lu, Yang ;
Martys, Nicos ;
Sakulich, Aaron R. ;
Weiss, W. Jason .
CEMENT & CONCRETE COMPOSITES, 2013, 38 :65-74
[8]   MODELING THE LEACHING OF CALCIUM HYDROXIDE FROM CEMENT PASTE - EFFECTS ON PORE-SPACE PERCOLATION AND DIFFUSIVITY [J].
BENTZ, DP ;
GARBOCZI, EJ .
MATERIALS AND STRUCTURES, 1992, 25 (153) :523-533
[9]   The system CaO-Al2O3-CaCl2-H2O at 23±2°C and the mechanisms of chloride binding in concrete [J].
Brown, P ;
Bothe, J .
CEMENT AND CONCRETE RESEARCH, 2004, 34 (09) :1549-1553
[10]  
BROWN PW, 1988, DURABILITY BUILD MAT, V5, P409