Imino-λ3-iodane-Triggered Oxidative Ring-Opening of 2H-Indazoles to ortho-N-Acylsulfonamidated Azobenzenes

被引：9

作者：

Bhattacharjee, Suvam ^{[1
]}

Hajra, Alakananda ^{[1
]}

机构：

[1] Dept Chem, 30190 Visva Bharati, Santini Ketan 731235, West Bengal, India

来源：

ORGANIC LETTERS | 2023年 / 25卷 / 22期

关键词：

METAL-FREE; AMINATION; CHEMISTRY; ANALOGS; OXIDES;

D O I：

10.1021/acs.orglett.3c01498

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An iminoiodane-enabled oxidative ring-opening of 2H-indazoles via C-N bond cleavage has been developedundermetal-free reaction conditions. This methodology afforded a new arrayof unsymmetrical ortho-N-acylsulfonamidatedazobenzenes with a wide functional group tolerance in good yields.The reaction potentially proceeds through the formation of a zwitterionicadduct, which is formed by the reaction between 2H-indazoles and iminoiodane.

引用

页码：4183 / 4187

页数：5

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