Bimetallic CuO-ZnO Hybrid Nanocomposite Materials for Efficient Remediation of Environmental Pollutants

被引:0
|
作者
Rudresha, K. [1 ,2 ]
Hussain, A. Zahir [2 ]
Ravikumar, C. R. [3 ]
Kumar, M. R. Anil [3 ]
Kumar, A. Naveen [4 ]
Manjunatha, A. S. [5 ]
Nagaswarupa, H. P. [6 ]
Amulya, Shilpa [3 ]
Murthy, H. C. Ananda [7 ,8 ]
Miret, Mireia Mallandrich [9 ]
Azad, Abul Kalam [10 ]
Madkhali, O. [11 ]
Aljabri, Mahmood D. [12 ]
Marwani, Hadi M. [13 ]
Rahman, Mohammed M. [13 ,14 ]
机构
[1] VTU, Jyothi Inst Technol, Dept Chem, Bangalore 560082, Karnataka, India
[2] Bharathidasan Univ, Jamal Mohamed Coll, Res Ctr, Dept Chem, Trichy 620020, Tamilnadu, India
[3] East West Inst Technol, Res Ctr, Dept Sci, Bangalore 560091, Karnataka, India
[4] VTU, South East Asian Coll Engn & Technol, Res Ctr, Dept Phys, Bangalore 560049, Karnataka, India
[5] VTU, Don Bosco Inst Technol, Dept Chem, Bengaluru 560074, India
[6] Davanagere Univ, Dept Studies Chem, Davanagere 577007, Karnataka, India
[7] Adama Sci & Technol Univ, Sch Appl Nat Sci, Dept Appl Chem, POB 1888, Adama, Ethiopia
[8] Saveetha Univ, Saveetha Dent Coll & Hosp, Saveetha Inst Med & Tech Sci SIMAT, Dept Prosthodont, Chennai 600077, Tamil Nadu, India
[9] Univ Barcelona, Fac Pharm & Food Sci, Dept Pharm Pharmaceut Technol & Phys Chem, Barcelona 08028, Spain
[10] Univ Coll MAIWP Int, Fac Pharm, Kuala Lumpur 68100, Malaysia
[11] Jazan Univ, Coll Sci, Dept Phys, POB 114, Jazan 45142, Saudi Arabia
[12] Umm Al Qura Univ, Univ Coll Al Jamoum, Dept Chem, Mecca 21955, Saudi Arabia
[13] King Abdulaziz Univ, Fac Sci, Dept Chem, POB 80203, Jeddah 21589, Saudi Arabia
[14] King Abdulaziz Univ, Ctr Excellence Adv Mat Res CEAMR, POB 80203, Jeddah 21589, Saudi Arabia
来源
CHEMISTRYSELECT | 2023年 / 8卷 / 29期
关键词
Arsenic detection; Binary CuO-ZnO nanocomposites; Dye degradation; Environmental remediation; X-ray diffraction; PHOTOCATALYTIC PROPERTIES; LEAF EXTRACT; NANOPARTICLES; NANOSTRUCTURES; DEGRADATION; WATER; PHOTOLUMINESCENCE; PERFORMANCE; ADSORPTION; SENSOR;
D O I
10.1002/slct.202300583
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pure CuO and 2-Dimentional CuO-ZnO nanocomposites (NCs) were effectively prepared by an ultrasound-assisted probe sonication route for different ratios of CuO and ZnO, and the multifunctional properties were investigated by the application of the advanced methods. XRD (X-ray diffraction) patterns revealed a crystallite size (D) range of 25 to 31 nm for pure CuO and CuO-ZnO NCs. According to calculations, the energy band gap value (Eg) for the NCs is between 2.15 and 2.48 eV. Under UV light irradiation, the photocatalytic degradation of pure CuO and CuO-ZnO NCs on Direct Green (DG) and Fast Blue (FB) dyes was assessed. 60 mg of the catalyst was added to 20 ppm solutions of DG and FB dye. The stock solution of the dyes was prepared 10, 15, 20 and 25 ppm of 250 ml dye solution. Electrochemical analysis using cyclic voltammetry revealed improved redox potential output in the electrode crafted with graphite powder in 0.1 N HCl electrolyte solution. These NCs were used because of their capacity to detect an extremely dangerous chemical like arsenic. The constructed electrode's lowest limit of detection was determined to be 110-3 mol/L. In general, vertical linearity was seen in all of the prepared nano-electrodes, especially above 150 ohms with real axis for pure CuO but beyond 100 ohms for doped electrodes. Based on our study, we conclude that the CuO and ZnO NCs, containing 10 % of ZnO, were the most effective photocatalyst for DG and FB dyes and electrochemical sensor for Arsenic.
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页数:15
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