Phenylglycine amphiphile-metal ion chiral supramolecular nanozymes for enantioselective catalysis

被引：7
|
作者：
Li, Dongying [1 ]
Gao, Cong [1 ]
Zhao, Cici [1 ]
Sun, Qingqing [1 ]
Xi, Zheng [1 ]
Han, Jie [1 ]
Guo, Rong [1 ]
机构：
[1] Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 34期
基金：
中国国家自然科学基金;
关键词：
ASYMMETRIC CATALYSIS;
D O I：
10.1039/d4cc00637b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
l/d-Phenylglycine amphiphiles and metal ions with peroxidase-like activity self-assembled into chiral nanoribbons, which act as efficient chiral supramolecular nanozymes for catalyzing the 3,4-dihydroxy-l/d-phenylalanine (l/d-DOPA) oxidation reactions. The catalytic efficiency and enantioselectivity are dominated by the chirality transfer and the synergistic effect between the metal ions and chiral nanoribbons. l/d-Phenylglycine chiral amphiphiles self-assembled with metal ions resulting in the construction of chiral supramolecular nanozymes (M/P), which exhibited high enantioselectivity and catalytic efficiency in the l/d-DOPA oxidation reactions.
引用
收藏
页码：4569 / 4572
页数：4
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