Phenylglycine amphiphile-metal ion chiral supramolecular nanozymes for enantioselective catalysis

被引：7

作者：

Li, Dongying ^{[1
]}

Gao, Cong ^{[1
]}

Zhao, Cici ^{[1
]}

Sun, Qingqing ^{[1
]}

Xi, Zheng ^{[1
]}

Han, Jie ^{[1
]}

Guo, Rong ^{[1
]}

机构：

[1] Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 34期

基金：

中国国家自然科学基金;

关键词：

ASYMMETRIC CATALYSIS;

D O I：

10.1039/d4cc00637b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

l/d-Phenylglycine amphiphiles and metal ions with peroxidase-like activity self-assembled into chiral nanoribbons, which act as efficient chiral supramolecular nanozymes for catalyzing the 3,4-dihydroxy-l/d-phenylalanine (l/d-DOPA) oxidation reactions. The catalytic efficiency and enantioselectivity are dominated by the chirality transfer and the synergistic effect between the metal ions and chiral nanoribbons. l/d-Phenylglycine chiral amphiphiles self-assembled with metal ions resulting in the construction of chiral supramolecular nanozymes (M/P), which exhibited high enantioselectivity and catalytic efficiency in the l/d-DOPA oxidation reactions.

引用

页码：4569 / 4572

页数：4

共 50 条

[21] Preparation and Characterization of Chiral Transition-Metal Dichalcogenide Quantum Dots and Their Enantioselective Catalysis
Zhang, Huan
He, Hui
Jiang, Xuemei
Xia, Zhining
Wei, Weili
ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (36) : 30680 - 30688
[22] Enantioselective catalysis;: 150:: Chiral-at-metal (η6-p-cymene)ruthenium(II) complexes of binaphthyl ligands -: Synthesis, characterization, and enantioselective catalysis
Brunner, H
Henning, F
Weber, M
Zabel, M
Carmona, D
Lahoz, FJ
SYNTHESIS-STUTTGART, 2003, (07): : 1091 - 1099
[23] Surface Chemistry Underpinning Enantioselective Heterogeneous Catalysis: Supramolecular Self-Assembly of Chiral Modifiers and Pro-Chiral Reagents on Ni{111}
Trant, Aoife G.
Baddeley, Christopher J.
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (04): : 1025 - 1030
[24] Chiral Amide Directed Assembly of a Diastereo- and Enantiopure Supramolecular Host and its Application to Enantioselective Catalysis of Neutral Substrates
Zhao, Chen
Sun, Qing-Fu
Hart-Cooper, William M.
Dipasquale, Antonio G.
Toste, F. Dean
Bergman, Robert G.
Raymond, Kenneth N.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (50) : 18802 - 18805
[25] A novel example of chiral counteranion induced enantioselective metal catalysis: The importance of ion-pairing in copper-catalyzed olefin aziridination and cyclopropanation
Llewellyn, DB
Adamson, D
Arndtsen, BA
ORGANIC LETTERS, 2000, 2 (26) : 4165 - 4168
[26] ENANTIOSELECTIVE CATALYSIS USING ANSA-BIS(INDENYL)METAL COMPLEXES CONTAINING CHIRAL BRIDGING GROUPS
HALTERMAN, RL
CHEN, Z
COLLETTI, SL
LOTMAN, ML
RAMSEY, T
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 203 : 49 - INOR
[27] Bioinspired enantioselective catalysis: Racemic or achiral metal complexes grafted on mesoporous material functionalized with chiral molecules
Cortial, Guillaume
Goettmann, Frederic
Mercier, Francois
Le Floch, Pascal
Sanchez, Clement
CATALYSIS COMMUNICATIONS, 2007, 8 (03) : 215 - 219
[28] Cooperative Transition-Metal and Chiral Bronsted Acid Catalysis: Enantioselective Hydrogenation of Imines To Form Amines
Zhou, Shaolin
Fleischer, Steffen
Junge, Kathrin
Beller, Matthias
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (22) : 5120 - 5124
[29] Tethered Counterion-Directed Catalysis: Merging the Chiral Ion-Pairing and Bifunctional Ligand Strategies in Enantioselective Gold(I) Catalysis
Marinetti, Angela (angela.marinetti@cnrs.fr), 1600, American Chemical Society (142):
[30] Tethered Counterion-Directed Catalysis: Merging the Chiral Ion-Pairing and Bifunctional Ligand Strategies in Enantioselective Gold(I) Catalysis
Zhang, Zhenhao
Smal, Vitalii
Retailleau, Pascal
Voituriez, Arnaud
Frison, Gilles
Marinetti, Angela
Guinchard, Xavier
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (08) : 3797 - 3805

← 1 2 3 4 5 →