An anionic In(III)-MOF for efficient adsorption of CO2 from CO2/N2 mixture and dye removal

Efficient adsorption of CO2 and dye molecules is crucial for reducing carbon emission and environmental pollution. Metal-Organic Frameworks (MOFs) are considered to be the ideal candidates for gas adsorption material because of their designability. In this work, a new In(III)-MOF (HBU-22) was synthesized by the reaction of a tetracarboxylic acid ligand (H4L, 9,9 '-bicarbazole-3,3 ',6,6 '-tetracarboxylic acid) with In3+ ions, which shows a three-dimensional (3D) coordination network. The saturated adsorption capacity of CO2 and N-2 are 21.11 cm(3).g(-1) and 0.66 cm(3).g(-1) at ambient condition (298 K, 100 kPa). And the higher IAST selectivity of CO2/N-2 (v/v, 15:85) reaches 347.37, exceeding that of most MOFs. Furthermore, it can also capture C2H2 with the maximum uptake of 42.80 cm(3) g(-1). More interestingly, HBU-22 as an anionic framework, which can selectively adsorb Rhodamine B (RhB) within 250 s with the maximum adsorption capacity of 105.04 mg.g(-1). Further studies show that higher gas adsorption capacity is mainly related to the larger Q(st) of the gas, while its adsorption of Rhodamine B (RhB) is mainly due to ion exchange mechanism.