The effects of Ca on the microstructure, mechanical and corrosion properties of extruded Mg-2Zn-0.5Mn alloy

被引:9
作者
Ma, Deqing [1 ]
Luan, Shiyu [1 ]
Jin, Peipeng [1 ]
Sun, Lingxiong [1 ]
Wang, Jinhui [1 ]
机构
[1] Qinghai Univ, Qinghai Prov Engn Res Ctr High Performance Light M, Qinghai Prov Key Lab New Light Alloys, Xining 810016, Peoples R China
来源
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T | 2023年 / 25卷
关键词
Mg-Zn-Mn-Ca alloy; Ca2Mg6Zn3; phase; Hot-extruded; Microstructure; Mechanical properties; Corrosion properties; HOT DEFORMATION-BEHAVIOR; MG ALLOY; TEXTURE; AZ31;
D O I
10.1016/j.jmrt.2023.06.075
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this study, the microstructure, mechanical properties and corrosion behavior of as-extruded Mg-2Zn-0.5Mn-xCa (x=0, 0.2, 0.4) alloys were investigated. The results showed that alloying with Ca refined the grains of the extruded rods and increased the unrecrystallized region, which leaded to an increase in ultimate tensile strength and a decrease in elongation. With the addition of Ca, the overall texture intensity of the alloys increase, and it is found that the texture of the alloys is mainly determined by the coarse deformed grains. The corrosion experiment of the alloys in hanks balanced salt solution (HBSS) shows that the corrosion product film of the alloys becomes denser with the addition of Ca. At the same time, the addition of Ca element introduces Ca2Mg6Zn3 phase, which reduces local corrosion, the corrosion resistance is improved. (c) 2023 The Authors. Published by Elsevier B.V.This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
引用
收藏
页码:2880 / 2889
页数:10
相关论文
共 33 条
[1]   Investigation on corrosion behavior and mechanical properties of an extruded Mg-Zn-Al-Sn-Mn alloy [J].
Bao, Yihao ;
Chen, Liang ;
Tang, Jianwei ;
Li, Zhigang ;
Zhao, Guoqun ;
Zhang, Cunsheng .
MATERIALS CHARACTERIZATION, 2021, 180
[2]   Microstructure and mechanical and corrosion properties of hot-extruded Mg-Zn-Ca-(Mn) biodegradable alloys [J].
Bazhenov, V. E. ;
Li, A., V ;
Komissarov, A. A. ;
Koltygin, A., V ;
Tavolzhanskii, S. A. ;
Bautin, V. A. ;
Voropaeva, O. O. ;
Mukhametshina, A. M. ;
Tokar, A. A. .
JOURNAL OF MAGNESIUM AND ALLOYS, 2021, 9 (04) :1428-1442
[3]   The relation between microstructure and corrosion behavior of AZ80 Mg alloy following different extrusion temperatures [J].
Ben-Haroush, M. ;
Ben-Hamu, G. ;
Eliezer, D. ;
Wagner, L. .
CORROSION SCIENCE, 2008, 50 (06) :1766-1778
[4]   A Compilation of Corrosion Potentials for Magnesium Alloys [J].
Cain, T. ;
Bland, L. G. ;
Birbilis, N. ;
Scully, J. R. .
CORROSION, 2014, 70 (10) :1043-1051
[5]   Corrosion behaviour in salt spray and in 3.5% NaCl solution saturated with Mg(OH)2 of as-cast and solution heat-treated binary Mg-X alloys: X = Mn, Sn, Ca, Zn, Al, Zr, Si, Sr [J].
Cao, Fuyong ;
Shi, Zhiming ;
Song, Guang-Ling ;
Liu, Ming ;
Atrens, Andrej .
CORROSION SCIENCE, 2013, 76 :60-97
[6]   Hot deformation behavior and processing map of a new type Mg-6Zn-1 Gd-1Er alloy [J].
Che, Bo ;
Lu, Liwei ;
Kang, Wei ;
Luo, Jun ;
Ma, Min ;
Liu, Longfei .
JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 862
[7]   Effect of Mn addition on corrosion properties of biodegradable Mg-4Zn-0.5Ca-xMn alloys [J].
Cho, Dae Hyun ;
Lee, Byoung Woo ;
Park, Jin Young ;
Cho, Kyung Mox ;
Park, Ik Min .
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 695 :1166-1174
[8]   The microstructure, texture and mechanical properties of extruded Mg-5.3Zn-0.2Ca-0.5Ce (wt%) alloy [J].
Du, Y. Z. ;
Qiao, X. G. ;
Zheng, M. Y. ;
Wu, K. ;
Xu, S. W. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2015, 620 :164-171
[9]   Effect of the Ca2Mg6Zn3 Phase on the Corrosion Behavior of Biodegradable Mg-4.0Zn-0.2Mn-xCa Alloys in Hank's Solution [J].
Fu, Junjian ;
Du, Wenbo ;
Liu, Ke ;
Du, Xian ;
Zhao, Chenchen ;
Liang, Hongxing ;
Mansoor, Adil ;
Li, Shubo ;
Wang, Zhaohui .
MATERIALS, 2022, 15 (06)
[10]   Precipitation-hardened Mg-Ca-Zn alloys with superior creep resistance [J].
Gao, X ;
Zhu, SM ;
Muddle, BC ;
Nie, JF .
SCRIPTA MATERIALIA, 2005, 53 (12) :1321-1326