Analysis of the Influence of Quantum Effects on Optical Characteristics of Plasmonic Nanoparticles Based on the Discrete Sources Method

The discrete sources method is adapted to the study of surface quantum effects based on mesoscopic boundary conditions with Feibelman parameters. A comparative analysis of the influence of bulk nonlocal effects and surface effects on optical characteristics of gold and silver nanoparticles is carried out using the generalized nonlocal optical response model. It is established that allowance for the nonlocal effect in the noble metals always leads to a reduced amplitude of the surface plasmon resonance (SPR) and its blue shift, while the surface effect depends substantially on the geometry of the particles. To a large degree, the mesoscopic boundary conditions recover the SPR amplitude as compared with the bulk nonlocal effect. This difference is especially noticeable in the field enhancement factor on the surface of the particles. Additionally, substantial differences in the SPR behavior for gold and silver particles are found in the case of mesoscopic boundary conditions.